Statement I p-hydroxybenzoic acid has a lower boiling point than o-hydroxybenzoic acid.
Statement II o-hydroxybenzoic acid has intramolecular hydrogen bonding.

The nitrogen containing compound produced in the reaction of $\mathrm{H}\mathrm{N}{\mathrm{O}}_3$ with ${\mathrm{P}}_4{\mathrm{O}}_{10}$

A sample \((5.6 \mathrm{~g})\) containing iron is completely dissolved in cold dilute \(\mathrm{HCl}\) to prepare a \(250 \mathrm{~mL}\) of solution. Titration of \(25.0 \mathrm{~mL}\) of this solution requires \(12.5 \mathrm{~mL}\) of \(0.03 \mathrm{M} \mathrm{KMnO}_{4}\) solution to reach the end point. Number of moles of \(\mathrm{Fe}^{2+}\) present in \(250 \mathrm{~mL}\) solution is \(\mathbf{x} \times 10^{-2}\) (consider complete dissolution of \(\mathrm{FeCl}_{2}\) ). The amount of iron present in the sample is \(\mathbf{y} \%\) by weight.
(Assume: \(\mathrm{KMnO}_{4}\) reacts only with \(\mathrm{Fe}^{2+}\) in the solution Use: Molar mass of iron as \(56 \mathrm{~g} \mathrm{~mol}^{-1}\) )
The value of $\mathrm{x}$ is________ .

Paragraph:
The noble gases have closed-shell electronic configuration and are monoatomic gases under normal conditions. The low boiling points of the lighter noble gases are due to weak dispersion forces between the atoms and the absence of other interatomic interactions.
The direct reaction of xenon with fluorine leads to a series of compounds with oxidation numbers \(+2,+4\) and \(+6 . \mathrm{XeF}_4\) reacts violently with water to give \(\mathrm{XeO}_3\). The compounds of xenon exhibit rich stereochemistry and their geometries can be deduced considering the total number of electron pairs in the valence shell.
Question:
\(\mathrm{XeF}_4\) and \(\mathrm{XeF}_6\) are expected to be

List-I includes starting materials and reagents of selected chemical reactions. List-II gives structures of compounds that may be formed as intermediate products and/or final products from the reactions of List-I.

List-I	List-II
(I)	$\left(\mathrm{P}\right)$
(II)	$\left(\mathrm{Q}\right)$
(III)	$\left(\mathrm{R}\right)$
(IV)	$\left(\mathrm{S}\right)$
	$\left(\mathrm{T}\right)$
	$\left(\mathrm{U}\right)$

Which of the following options has correct combination considering List-I and List-II?

The given graphs/data I, II, III and IV represent general trends observed for different physisorption and chemisorption processes under mild conditions of temperature and presure. Which of the following

Consider the following reaction,
\(2 \mathrm{H}_2(\mathrm{~g})+2 \mathrm{NO}(\mathrm{g}) \rightarrow \mathrm{N}_2(\mathrm{~g})+2 \mathrm{H}_2 \mathrm{O}(\mathrm{g})\)
which follows the mechanism given below:
\(2 \mathrm{NO}(\mathrm{g}) \stackrel{k_1}{\underset{k_{-1}}{\rightleftharpoons}} \mathrm{N}_2 \mathrm{O}_2(\mathrm{~g})\) \(\quad\) (fast equlibrium)
\(\mathrm{N}_2 \mathrm{O}_2(\mathrm{~g})+\mathrm{H}_2(\mathrm{~g}) \xrightarrow{k_2} \mathrm{~N}_2 \mathrm{O}(\mathrm{g})+\mathrm{H}_2 \mathrm{O}(\mathrm{g})\) \(\quad\)(slow reaction)
\(\mathrm{N}_2 \mathrm{O}(\mathrm{g})+\mathrm{H}_2(\mathrm{~g}) \xrightarrow{k_3} \mathrm{~N}_2(\mathrm{~g})+\mathrm{H}_2 \mathrm{O}(\mathrm{g})\) \(\quad\) (fast reaction)
The order of the reaction is_____

A composite block is made of slabs \(A, B, C, D\) and \(E\) of different thermal conductivities (given in terms of a constant, \(K\) ) and sizes (given in terms of length, \(L\) ) as shown in the figure. All slabs are of same width. Heat \(Q\) flows only from left to right through the blocks. Then, in steady state

The number of $-{\mathrm{CH}}_{2-}$ (methylene) groups in the product formed from the following reaction sequence is _____ .

Let \(X=\left({ }^{10} C_1\right)^2+2\left({ }^{10} C_2\right)^2+3\left({ }^{10} C_3\right)^2+\ldots+\) \(10\left({ }^{10} C_{10}\right)^2\), where \({ }^{10} C_r, r \in\{1,2, \ldots, 10\}\) denote binomial coefficients. Then, the value of \(\frac{1}{1430} X\) is _____________.

In a study about a pandemic, data of $900$ persons was collected. It was found that $190$ persons had symptom of fever, $220$ persons had symptom of cough, $220$ persons had symptom of breathing problem, $330$ persons had symptom of fever or cough or both, $350$ persons had symptom of cough or breathing problem or both, $340$ persons had symptom of fever or breathing problem or both, $30$ persons had all three symptoms (fever, cough and breathing problem). If a person is chosen randomly from these $900$ persons, then the probability that the person has at most one symptom is ______.

For the electrochemical cell, $\text{Mg(s)}\left|{\text{Mg}}^{\text{2+}}\left(\text{aq,1}\text{M}\right)\right|\left|{\text{Cu}}^{\text{2+}}\left(\text{aq,1}\text{M}\right)\right|\text{Cu }\left(\text{s}\right)$ the standard emf of the cell is $\text{2}\text{.70 V}$ at $\text{300 K}\text{.}$ When the concentration of ${\text{Mg}}^{\text{2+}}$ is changed to $\text{x M,}$ the cell potential changes to $\text{2}\text{.67 V}$ at $\text{300 K}\text{.}$ The value of $\text{x}$ is ________.
(given, $\frac{\text{F}}{\text{R}}{\text{=11500 K V}}^{-\text{1}}\text{,}$ where $\text{F}$ is the Faraday constant and $\text{R}$ is the gas constants, $\text{ln}\left(\text{10}\right)\text{=}\text{2}\text{.30}$ )

A uniform circular disc of mass 1.5 kg and radius 0.5 m is initially at rest on a horizontal frictionless surface. Three forces of equal magnitude $\mathrm{F}\mathrm{}=\mathrm{}0.5\mathrm{}\mathrm{N}$ are applied simultaneously along the three sides of an equilateral triangle XYZ with its vertices on the perimeter of the disc (see figure). One second after applying the forces, the angular speed of the disc in rad ${\mathrm{s}}^{-1}$ is