Statement I Alkali metals dissolve in liquid ammonia to give blue solutions. Statement II Alkali metals in liquid ammonia give solvated species of the type \(\left(M\left(\mathrm{NH}_3\right)_n\right]^{+}(M=\) alkali metals \()\).

The correct order of the wavelength maxima of the absorption band in the ultraviolet-visible region for the given complexes is

Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes (I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.

	List – I		List – II
A.		P.
B.		Q.
C.		R.
D.		S.

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option.

	List I		List II
$\left(\mathrm{P}\right)$	Etard reaction	$1$	$\mathrm{Acetophenone} \stackrel{\mathrm{Zn}-\mathrm{Hg},\mathrm{HCl}}{\to }$
$\left(\mathrm{Q}\right)$	Gattermann reaction	$2$	$\mathrm{Toluene} \underset{\left(\mathrm{ii}\right) {\mathrm{SOCl}}_2 }{\overset{\left(\mathrm{i}\right) {\mathrm{KMnO}}_4, \mathrm{KOH},\mathbf{ }\mathrm{\Delta } }{\to }}$
$\left(\mathrm{R}\right)$	Gattermann-Koch reaction	$3$	$\mathrm{Benzene} \underset{\mathrm{Anhyd}. {\mathrm{AlCl}}_3}{\overset{{\mathrm{CH}}_3\mathrm{Cl}}{\to }}$
$\left(\mathrm{S}\right)$	Rosenmund reduction	$4$	$\mathrm{Aniline} \frac{{\mathrm{NaNO}}_2 /\mathrm{HCl}}{273-278 \mathrm{K}}$
		$5$	$\mathrm{Phenol} \stackrel{\mathrm{Zn},\mathrm{\Delta }}{\to }$

Among the following, the surfactant that will form micelles in aqueous solution at the lowest molar concentration at ambient conditions is

${\mathrm{H}}_2 \mathrm{S}$ ($5$ moles) reacts completely with acidified aqueous potassium permanganate solution. In this reaction, the number of moles of water produced is $\mathbf{x}$, and the number of moles of electrons involved is $\mathbf{y}$. The value of $(\mathrm{x}+\mathrm{y})$ is

The reagent(s) for the following conversion,

is/are

A hydrogen atom, initially at rest in its ground state, absorbs a photon of frequency \(v_1\) and ejects the electron with a kinetic energy of 10 eV . The electron then combines with a positron at rest to form a positronium atom in its ground state and simultaneously emits a photon of frequency \(v_2\). The center of mass of the resulting positronium atom moves with a kinetic energy of 5 eV . It is given that positron has the same mass as that of electron and the positronium atom can be considered as a Bohr atom, in which the electron and the positron orbit around their center of mass. Considering no other energy loss during the whole process, the difference between the two photon energies (in eV ) is \(\qquad\)

A student is performing an experiment using a resonance column and a tuning fork of frequency \(244 s^{-1}\). He is told that the air in the tube has been replaced by another gas (assume that the column remains filled with the gas). If the minimum height at which resonance occurs is \((0.350 \pm 0.005) m\), the gas in the tube is (Useful information: \(\sqrt{167\text{ RT}}=640\text{ J}^{\frac{1}{2}}\text{ mol}^{-\frac{1}{2}} ;\) \(\sqrt{140\text{ RT}}=590\text{ J}^{\frac{1}{2}}\text{ mole}^{-\frac{1}{2}}\) . The molar masses M in grams are given in the options. Take the values of \(\sqrt{\frac{10}{\text M }}\) for each gas as given there.)

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There are some deposits of nitrates and phosphates in earth's crust. Nitrates are more soluble in water. Nitrates are difficult to reduce under the laboratory conditions but microbes do it easily. Ammonia forms large number of complexes with transition metal ions. Hybridisation easily explains the ease of sigma donation capability of \(\mathrm{NH}_3\) and \(\mathrm{PH}_3\). Phosphine is a flammable gas and is prepared from white phosphorus.
Question:
White phosphorus on reaction with \(\mathrm{NaOH}\) gives \(\mathrm{PH}_3\) as one of the products. This is a

Two identical concave mirrors each of focal length \(f\) are facing each other as shown in the schematic diagram. The focal length \(f\) is much larger than the size of the mirrors. A glass slab of thickness \(t\) and refractive index \(n_0\) is kept equidistant from the mirrors and perpendicular to their common principal axis. A monochromatic point light source \(S\) is embedded at the center of the slab on the principal axis, as shown in the schematic diagram. For the image to be formed on \(S\) itself, which of the following distances between the two mirrors is/are correct:

Area of the region $\{\left(x,y\right)\in R^2: y\ge \sqrt{\left|x+3\right|},$ $5y\le x+9\le 15\}$ is equal to

A ray of light, travelling in the direction $\frac{1}{2}\left(\hat{\mathrm{i}}+\sqrt{3} \hat{\mathrm{j}}\right)$, is incident on a plane mirror. After reflection, it travels along the direction $\frac{1}{2}\left(\hat{\mathrm{i}}-\sqrt{3}\widehat{ \mathrm{j}}\right)$. The angle of incidence is