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An aqueous solution of a mixture of two inorganic salts, when treated with dilute \(H C\) ?, gave a precipitate \((\boldsymbol{P})\) and a filtrate \((\boldsymbol{Q})\). The precipitate \(\boldsymbol{P}\) was found to dissolve in hot water. The filtrate \((\boldsymbol{Q})\) remained unchanged, when treated with \(\mathrm{H}_{2} \mathrm{~S}\) in a dilute mineral acid medium. However, it gave a precipitate \((\boldsymbol{R})\) with \(H_{2} S\) in an ammoniacal medium. The precipitate \(\boldsymbol{R}\) gave a coloured solution \((\boldsymbol{S})\), when treated with \(\mathrm{H}_{2} \mathrm{O}_{2}\) in an aqueous \(\mathrm{NaOH}\) medium.

Question:
The precipitate \(\boldsymbol{P}\) contains

Assuming that Hund's rule is violated, the bond order and magnetic nature of the diatomic molecule \(\mathrm{B}_2\) is

The entropy versus temperature plot for phases $\alpha$ and $\beta$ at $1$ bar pressure is given. ${\mathrm{S}}_{\mathrm{T}}$ and ${\mathrm{S}}_0$ are entropies of the phases at temperatures $\mathrm{T}$ and $0 \mathrm{K}$, respectively. The transition temperature for $\alpha$ to $\beta$ phase change is $600 \mathrm{K}$ and ${\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}-{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}=1 \mathrm{J} {\mathrm{mol}}^{-1} {\mathrm{K}}^{-1}$. Assume $\left({\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}-{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}\right)$ is independent of temperature in the range of $200$ to $700 \mathrm{K}.{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}$ and ${\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}$ are heat capacities of $\alpha$ and $\beta$ phases, respectively.
The value of entropy change, ${\mathrm{S}}_{\beta }-{\mathrm{S}}_{\alpha }$ (in ${\mathrm{Jmol}}^{-1} {\mathrm{K}}^{-1}$ ), at $300 \mathrm{K}$ is [Use: $\ln 2=0.69$0. Given: ${\mathrm{S}}_{\beta }-{\mathrm{S}}_{\alpha }=0$ at $0 \mathrm{K}$]

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Tollen's reagent is used for the detection of aldehyde when a solution of \(\mathrm{AgNO}_3\) is added to glucose with \(\mathrm{NH}_4 \mathrm{OH}\) then gluconic acid is formed
\(\mathrm{Ag}^{+}+e^{-} \rightarrow \mathrm{Ag} E_{\text {red }}^{\circ}=0.8 \mathrm{~V} \)
\( \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{H}_2 \mathrm{O} \rightarrow \text { Gluconic acid }\left(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_7\right)\) \(+~2 \mathrm{H}^{+}+2 e^{-} ; -E_{\mathrm{red}}^{\circ}=-0.05 \mathrm{~V} \)
\( \mathrm{Ag}\left(\mathrm{NH}_3\right)_2^{+}+e^{-} \rightarrow \mathrm{Ag}(s)+2 \mathrm{NH}_3 ; E_{\mathrm{red}}^{\circ}\) \(=0.337 \mathrm{~V}\)
[Use \(2.303 \times \frac{R T}{F}=0.0592\) and \(\frac{F}{R T}=38.92\) at \(298 \mathrm{~K}\)]
Question:
\(2 \mathrm{Ag}^{+}+\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{H}_2 \mathrm{O} \rightarrow 2 \mathrm{Ag}(\mathrm{s})\) \(+~\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_4+2 \mathrm{H}^{+}\). Find \(\ln \mathrm{K}\) of this reaction.

For the process \(\mathrm{H}_2 \mathrm{O}(\mathrm{l})\) (1 bar, \(\left.273 \mathrm{~K}\right) \longrightarrow \mathrm{H}_2 \mathrm{O}(\mathrm{g})\) (1 bar, \(\left.373 \mathrm{~K}\right)\), the correct set of thermodynamic parameters is

Among the following, the number of reaction(s) that produce(s) benzaldehyde is

The major product of the following reaction is

Let $f :\left[0, 4\pi \right]\to \left[0, \pi \right]$ be defined by $f\left(x\right)={\cos }^{-1}\left(\cos x\right).$ The number of points $x \in \left[0, 4\pi \right]$ satisfying the equation $f\left(x\right)=\frac{10-x}{10}$ is_________

${\mathrm{H}}_2 \mathrm{S}$ ($5$ moles) reacts completely with acidified aqueous potassium permanganate solution. In this reaction, the number of moles of water produced is $\mathbf{x}$, and the number of moles of electrons involved is $\mathbf{y}$. The value of $(\mathrm{x}+\mathrm{y})$ is

Let \(f(x)=2+\cos x\) for all real \(x\).
Statement I For each real \(t\), there exists a point \(c\) in \([t, t+\pi]\) such that \(f^{\prime}(c)=0\).
Statement II \(f(t)=f(t+2 \pi)\) for each real \(t\).

A glass tube of uniform internal radius \((r)\) has a valve separating the two identical ends. Initially, the valve is in a tightly closed position. End 1 has a hemispherical soap bubble of radius \(r\). End 2 has sub-hemispherical soap bubble as shown in figure. Just after opening the valve,

Consider the reaction sequence from $\mathrm{P}$ to $\mathrm{Q}$ shown below. The overall yield of the major product $\mathrm{Q}$ from $\mathrm{P}$ $75\%.$ What is the amount in grams of $\mathrm{Q}$ obtained from $9.3 \mathrm{mL}$ $\mathrm{P}$? (Use density of $=1.00{\text{\hspace{0.33em}g\hspace{0.33em}mL}}^{-1};$ Molar mass of $\mathrm{C}=12.0,\mathrm{H}=1.0,\mathrm{O}=16.0$ and $\mathrm{N}=14.0 \mathrm{g} {\mathrm{mol}}^{-1}$)

The compound (s) having peroxide linkage is(are) :