JEE Advanced · Chemistry · 12. p Block (G13-14)
Match the following

- A (A) Q,S, (B) S, (C) R, (D) Q,R
- B (A) Q,S, (B) R, (C) S, (D) Q
- C (A) P,R, (B) P, R, (C) R, (D) Q,R
- D (A) P,R, (B) P, (C) R, (D) Q,R
Answer & Solution
Correct Answer
(A) (A) Q,S, (B) S, (C) R, (D) Q,R
Step-by-step Solution
Detailed explanation
A match with \(\boldsymbol{Q}, \boldsymbol{S} \quad \mathrm{Bi}^{3+}+\mathrm{H}_2 \mathrm{O} \longrightarrow[\mathrm{BiO}]^{+}+2 \mathrm{H}^{+}\)
B match with \(\boldsymbol{S} \mathrm{NaAlO}_2+2 \mathrm{H}_2 \mathrm{O} \longrightarrow \mathrm{Al}(\mathrm{OH})_3+\mathrm{NaOH}\)
C match with \(\boldsymbol{R} \quad 2 \mathrm{SiO}_4^{4-}+2 \mathrm{H}^{+} \longrightarrow \mathrm{Si}_2 \mathrm{O}_7^{6-}+\mathrm{H}_2 \mathrm{O}\) Pyrosilicate is formed by treating orthosilicate with acid.
D match with \(\boldsymbol{Q}, \boldsymbol{R} \mathrm{Na}_2 \mathrm{~B}_4 \mathrm{O}_7 \underset{\text { or } \mathrm{H}_2 \mathrm{SO}_4}{\stackrel{\mathrm{HCl}}{\mathrm{O}_3}} \mathrm{H}_3 \mathrm{BO}_3\)
\(\mathrm{Na}_2 \mathrm{~B}_4 \mathrm{O}_4 \stackrel{\mathrm{H}_2 \mathrm{O}}{\longrightarrow} \mathrm{H}_3 \mathrm{BO}_3\)
B match with \(\boldsymbol{S} \mathrm{NaAlO}_2+2 \mathrm{H}_2 \mathrm{O} \longrightarrow \mathrm{Al}(\mathrm{OH})_3+\mathrm{NaOH}\)
C match with \(\boldsymbol{R} \quad 2 \mathrm{SiO}_4^{4-}+2 \mathrm{H}^{+} \longrightarrow \mathrm{Si}_2 \mathrm{O}_7^{6-}+\mathrm{H}_2 \mathrm{O}\) Pyrosilicate is formed by treating orthosilicate with acid.
D match with \(\boldsymbol{Q}, \boldsymbol{R} \mathrm{Na}_2 \mathrm{~B}_4 \mathrm{O}_7 \underset{\text { or } \mathrm{H}_2 \mathrm{SO}_4}{\stackrel{\mathrm{HCl}}{\mathrm{O}_3}} \mathrm{H}_3 \mathrm{BO}_3\)
\(\mathrm{Na}_2 \mathrm{~B}_4 \mathrm{O}_4 \stackrel{\mathrm{H}_2 \mathrm{O}}{\longrightarrow} \mathrm{H}_3 \mathrm{BO}_3\)
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