Among the electrolytes \(\mathrm{Na}_2 \mathrm{SO}_4, \mathrm{CaCl}_2 \quad \mathrm{Al}_2\left(\mathrm{SO}_4\right)_3\) and \(\mathrm{NH}_4 \mathrm{Cl}\), the most effective coagulating agent for \(\mathrm{Sb}_2 \mathrm{~S}_3\) sol is

The correct statement(s) about the compound, \(\mathrm{H}_3 \mathrm{C}(\mathrm{HO}) \mathrm{HC}-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}\) (OH) \(\mathrm{CH}_3(\mathrm{X})\) is (are)

For the process ${\mathrm{H}}_2\mathrm{O}\mathrm{ }\left(\mathcal{l}\right)\to {\mathrm{H}}_2\mathrm{O}\left(\mathrm{g}\right)\mathrm{ }$ at $\mathrm{T}={100}^{\mathrm{o}}\mathrm{C}\mathrm{ }$ and 1 atmosphere pressure, the correct choice is

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Treatment of compound \(\mathbf{O}\) with \(\mathrm{KMnO}_{4} / \mathrm{H}^{+}\)gave \(\mathbf{P}\), which on heating with ammonia gave \(\mathbf{Q}\). The compound \(\mathbf{Q}\) on treatment with \(\mathrm{Br}_{2} / \mathrm{NaOH}\) produced \(\mathbf{R}\). On strong heating, \(\mathbf{Q}\) gave \(\mathbf{S}\), which on further treatment with ethyl \(2-\)bromopropanoate in the presence of \(\mathrm{KOH}\) followed by acidification, gave a compound \(\mathbf{T}\).


Question :
The compound \(\mathbf{T}\) is

Consider the kinetic data given in the following table for the reaction $\mathrm{A}+\mathrm{B}+\mathrm{C}\to$ Product.

Ex peri ment No.	\([\text A]\) \((\text{mol}\) \(\text{dm} ^{-3})\)	\([\text B]\) \((\text{mol}\) \(\text{dm} ^{-3})\)	\([\text C]\) \((\text{mol}\) \(\text{dm} ^{-3})\)	Rate of reaction \((\text{mol}\) \(\text{dm} ^{-3}\) \(\text s^{-1})\)
1	0.2	0.1	0.1	\(6.0 \times\) \(10^{-5}\)
2	0.2	0.2	0.1	\(6.0 \times \) \(10^{-5}\)
3	0.2	0.1	0.2	\(1.2 \times \) \(10^{-4}\)
4	0.3	0.1	0.1	\(9.0 \times \) \(10^{-5}\)

The rate of the reaction for $\left[\mathrm{A}\right]=0.15\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3},\mathrm{ }\left[\mathrm{B}\right]=0.25\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3}$ and $\left[\mathrm{C}\right]=0.15\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3}$ is found to be $\mathrm{Y}\times {10}^{-5}\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3}{\mathrm{s}}^{-1}.$ The value of $\mathrm{Y}$ is __________

For 'invert sugar', the correct statement(s) is (are)
(Given: specific rotations of $\left(+\right)-$sucrose, $\left(+\right)-$maltose, $\mathrm{L}-\left(-\right)-$glucose and $\mathrm{L}-\left(+\right)-$fructose in aqueous solution are $+\mathrm{ }{66}^{°},\mathrm{ }+{140}^{°},\mathrm{ }–{52}^{°}$ and $+\mathrm{ }{92}^{°}$, respectively)

Assuming $2\mathrm{s}\mathrm{ }–\mathrm{ }2\mathrm{p}$ mixing is NOT operative, the paramagnetic species among the following is

Six cards and six envelopes are numbered 1, 2, 3, 4, 5, 6 and cards are to be placed in envelopes so that each envelope contains exactly one card and no card is placed in the envelope bearing the same number and more over the card numbered 1 is always placed in envelope numbered 2. Then the number of ways it can be done is

Extraction of metal from the ore cassiterite involves

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\(P_{14-16}\) : Paragraph for Questions Nos. 14 to 16 A fixed thermally conducting cylinder has a radius \(R\) and height \(L_0\). The cylinder is open at its bottom and has a small hole at its top. A piston of mass \(M\) is held at a distance \(L\) from the top surface as shown in the figure. The atmospheric pressure is \(p_0\).

Question :
While the piston is at a distance \(2 L\) from the top, the hole at the top is sealed. The piston is then released, to a position where it can stay in equilibrium. In this condition, the distance of the piston from the top is

For the reaction, \(\mathbf{X}(s) \rightleftharpoons \mathbf{Y}(s)+\mathbf{Z}(g)\), the plot of \(\ln \frac{p_{\mathbf{Z}}}{p^{\theta}}\) versus \(\frac{10^{4}}{T}\) is given below (in solid line), where \(p_{\mathbf{Z}}\) is the pressure (in bar) of the gas \(\mathbf{Z}\) at temperature \(T\) and \(p^{\theta}=1\) bar.

(Given, \(\frac{\mathrm{d}(\ln K)}{\mathrm{d}\left(\frac{1}{T}\right)}=-\frac{\Delta H^{\theta}}{R}\), where the equilibrium constant, \(K=\frac{p_{z}}{p^{\theta}}\) and the gas constant, \(\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\) )
The value of $∆{\mathrm{S}}^{\mathrm{o}}$ (in $\mathrm{kJ} {\mathrm{mol}}^{-1}$) for the given reaction, at $1000 \mathrm{K}$ is ___.

The species having bond order different from that in \(\mathrm{CO}\) is

Two large circular discs separated by a distance of $0.01\mathrm{m}$ are connected to a battery via a switch as shown in the figure. Charged oil drops of density $900\mathrm{kg}{\mathrm{m}}^{-3}$ are released through a tiny hole at the centre of the top disc. Once some oil drops achieve terminal velocity, the switch is closed to apply a voltage of $200\mathrm{V}$ across the discs. As a result, an oil drop of radius $8\times {10}^{-7}\mathrm{m}$ stops moving vertically and floats between the discs. The number of electrons present in this oil drop is __________. (neglect the buoyancy force, take acceleration due to gravity $=10\mathrm{m}{\mathrm{s}}^{-2}$ and charge on an electron (e) $=1.6\times {10}^{-19}\mathrm{C}$)