Considering the reaction sequence given below, the correct statement(s) is(are)

For a reaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its equilibrium constant $\mathrm{K}$ in terms of change in entropy is described by:

The sum of the number of lone pairs of electrons on each central atom in the following species is \(\left[ TeBr _6\right]^{2-},\left[ Br F _2\right]^{+}, S N F_3\) and \(\left[ XeF _3\right]^{-}\)[Atomic number : \(N=7, F=9, S =16, B r=35,\) \(T e=52, X e=54]\)

Bleaching powder and bleach solution are produced on a large scale and used in several household products. The effectiveness of bleach solution is often measured by iodometry.
Question:
\(25 \mathrm{~mL}\) of household solution was mixed with \(30 \mathrm{~mL}\) of \(0.50\) M KI and \(10 \mathrm{~mL}\) of \(4 \mathrm{~N}\) acetic acid. In the titration of the liberated iodine, \(48 \mathrm{~mL}\) of \(0.25 \mathrm{~N~} \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}\) was used to reach the end point. The molarity of the household bleach solution is

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\(\mathbf{X}\) and \(\mathbf{Y}\) are two volatile liquids with molar weights of \(10 \mathrm{~g} \mathrm{~mol}^{-1}\) and \(40 \mathrm{~g} \mathrm{~mol}^{-1}\) respectively. Two cotton plugs, one soaked in \(\mathbf{X}\) and the other soaked in \(\mathbf{Y}\), are simultaneously placed at the ends of a tube of length \(L=24 \mathrm{~cm}\), as shown in the figure. The tube is filled with an inert gas at \(1\) atmosphere pressure and a temperature of \(300 \mathrm{~K}\). Vapours of \(\mathbf{X}\) and \(\mathbf{Y}\) react to form a product which is first observed at a distance \(\mathbf{d} \mathrm{~cm}\) from the plug soaked in \(\mathbf{X}\). Take \(\mathbf{X}\) and \(\mathbf{Y}\) to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.



Question:

The value of \(\mathbf{d}\) in \(\mathbf{c m}\) (shown in the figure), as estimated from Graham's law, is

Match the extraction processes listed in column I with metals listed in column II.

In the decay sequence:
${}_{92}{}^{238}\mathrm{U}\stackrel{-{\mathrm{x}}_1}{\to }{}_{90}{}^{234}\mathrm{T}\mathrm{h}\stackrel{-{\mathrm{x}}_2}{\to }{}_{91}{}^{234}\mathrm{P}\mathrm{a}\stackrel{-{\mathrm{x}}_3}{\to }{}_{\mathrm{ }}{}^{234}\mathrm{Z}\stackrel{-{\mathrm{x}}_4}{\to }{}_{90}{}^{234}\mathrm{T}\mathrm{h}$
${\mathrm{x}}_1,\mathrm{ }{\mathrm{x}}_2,\mathrm{ }{\mathrm{x}}_3$ and ${\mathrm{x}}_4$ are the particles/ radiation emitted by the respective isotopes. The correct option(s) is/are:

Statement I The total translational kinetic energy of all the molecules of a given mass of an ideal gas is \(1.5\) times the product of its pressure and its volume.
Statement II The molecules of a gas collide with each other and the velocities of the molecules change due to the collision.

The graph between \(1 / \lambda\) and stopping potential \((V)\) of three metals having work function \(\phi_1, \phi_2\) and \(\phi_3\) in an experiment of photoelectric effect is plotted as shown in the figure. Which of the following statement(s) is/are correct? [Here \(\lambda\) is the wavelength of the incident ray].

The correct statement(s) about surface properties is(are)

What is the order of basicity among the following compounds?

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Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite \(\left(\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}\right)\), atacamite \(\left(\mathrm{Cu}_2 \mathrm{Cl}(\mathrm{OH})_3\right)\), cuprite \(\left(\mathrm{Cu}_2 \mathrm{O}\right)\), copper glance \(\left(\mathrm{Cu}_2 \mathrm{~S}\right)\) and malachite \(\left(\mathrm{Cu}_2(\mathrm{OH})_2 \mathrm{CO}_3\right)\). However, 80\% of the world copper production comes from the ore chalcopyrite \(\left(\mathrm{CuFeS}_2\right)\). The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.
Question:
Partial roasting of chalcopyrite produces

Let \(S\) be the set of all seven-digit numbers that can be formed using the digits 0,1 and 2 . For example, 2210222 is in \(S\), but 0210222 is NOT in \(S\).
Then the number of elements \(x\) in \(S\) such that at least one the digits 0 and 1 appears exactly twice in \(x\), is equal to ______.