Bleaching powder and bleach solution are produced on a large scale and used in several household products. The effectiveness of bleach solution is often measured by iodometry.
Question:
\(25 \mathrm{~mL}\) of household solution was mixed with \(30 \mathrm{~mL}\) of \(0.50\) M KI and \(10 \mathrm{~mL}\) of \(4 \mathrm{~N}\) acetic acid. In the titration of the liberated iodine, \(48 \mathrm{~mL}\) of \(0.25 \mathrm{~N~} \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}\) was used to reach the end point. The molarity of the household bleach solution is

A colorless aqueous solution contains nitrates of two metals, $\mathrm{X}$ and $\mathrm{Y}$. When it was added to an aqueous solution of $\mathrm{NaCl}$, a white precipitate was formed. This precipitate was found to be partly soluble in hot water to give a residue $\mathrm{P}$ and a solution $\mathrm{Q}$. The residue $\mathrm{P}$ was soluble in aq. ${\mathrm{NH}}_3$ and also in excess sodium thiosulfate. The hot solution $\mathrm{Q}$ gave a yellow precipitate with $\mathrm{KI}$. The metals $\mathrm{X}$ and $\mathrm{Y}$, respectively, are

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The hydrogen-like species \(\mathrm{Li}^{2+}\) is in a spherically symmetric state \(S_1\) with one radial node. Upon absorbing light the ion undergoes transition to a state \(S_2\). The state \(S_2\) has one radial node and its energy is equal to the ground state energy of the hydrogen atom.
Question:
The state \(S_1\) is

At 300 K , an ideal dilute solution of a macromolecule exerts osmotic pressure that is expressed in terms of the height ( h ) of the solution (density \(=1.00 \mathrm{~g} \mathrm{~cm}^{-3}\) ) where h is equal to 2.00 cm . If the concentration of the dilute solution of the macromolecule is \(2.00 \mathrm{~g} \mathrm{dm}^{-3}\), the molar mass of the macromolecule is calculated to be \(\boldsymbol{X} \times 10^4 \mathrm{~g} \mathrm{~mol}^{-1}\). The value of \(\boldsymbol{X}\) is \(\qquad\) .
Use : Universal gas constant \((\mathrm{R})=8.3 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\) and acceleration due to gravity \((\mathrm{g})=10 \mathrm{~m} \mathrm{~s}^{-2}\)

The decomposition reaction $2{\mathrm{N}}_2{\mathrm{O}}_5\left(\mathrm{g}\right)\stackrel{ ∆ }{\to }2{\mathrm{N}}_2{\mathrm{O}}_4\left(\mathrm{g}\right)+{\mathrm{O}}_2\left(\mathrm{g}\right)$ is started in a closed cylinder under the isothermal isochoric condition at an initial pressure of $1 \mathrm{atm}$. After $\mathrm{Y}\times {10}^3\mathrm{ }\mathrm{s}$ , the pressure inside the cylinder is found to be $1.45\mathrm{ }\mathrm{a}\mathrm{t}\mathrm{m}$ . If the rate constant of the reaction is $5\times {10}^{-4}{\mathrm{s}}^{-1}$, assuming ideal gas behaviour, the value of $\mathrm{Y}$ is

Among cellulose, polyvinyl chloride, nylon and natural rubber, the polymer in which the intermolecular force of attraction is weakest in

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An aqueous solution of metal ion \(\mathbf{M} 1\) reacts separately with reagents \(\mathbf{Q}\) and \(\mathbf{R}\) in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral complexes with these reagents. Aqueous solution of \(\mathbf{M} 2\) on reaction with reagent \(\mathbf{S}\) gives white precipitate which dissolves in excess of \(\mathbf{S}\). The reactions are summarized in the scheme given below:


Question:
\(\mathbf{M} 1, \mathbf{Q}\) and \(\mathbf{R}\), respectively are

A spherical body of radius $\mathrm{R}$ consists of a fluid of constant density and is in equilibrium under its own gravity. If $\mathrm{P}\left(\mathrm{r}\right)$ is the pressure at $\mathrm{r}(\mathrm{r}<\mathrm{R})$ , then the correct option(s) is (are)

The wave function, \(\psi_{ n , 1, m_{ l }}\) is a mathematical function whose value depends upon spherical polar coordinates \(( r , \theta, \phi)\) of the electron and characterized by the quantum numbers \(n , 1\) and \(m _{ l }\). Here \(r\) is the distance from the nucleus, \(\theta\) is colatitude and \(\phi\) is azimuth. In the mathematical functions given in the Table, Z is the atomic number and \(a_0\) is Bohr radius

Column 1	Column 2	Column 3
(I) 1s orbital	\(\text {(i) } \psi_{ n , 1, m_1}\) \(\propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{3}{2}} e ^{-\left(\frac{ Zr }{ e _{ o }}\right)}\)	(P)
(II) 2s orbital	(ii) One radial node	(Q) Probability density at the nucleus \(\propto \frac{1}{ a _{ o }^3}\).
(III) \(2 p _{ z }\) orbital	\(\text {(iii) } \psi_{ n }, 1, m_{ l }\) \(\propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{5}{2}} re ^{-\left(\frac{ Zr }{2 a _{ o }}\right)} \cos \theta\)	(R) Probability density is maximum at the nucleus.
(IV) \(3 d_{ z }^2\) orbital	(iv) \(x y\)-plane is a nodal plane	(S) Energy needed to excite an electron from \(n =2\) state to \(n =4\) state is \(\frac{27}{32}\) times the energy needed to excite are electron from \(n =2\) state to \(n =6\) state.

For \(\text{He} ^{+}\)ion, the only incorrect combination

A simple telescope used to view distant objects has eyepiece and objective lens of focal lengths \(f_e\) and \(f_0\), respectively. Then

A person blows into open-end of a long pipe. As a result, a high pressure pulse of air travels down the pipe.

When this pulse reaches the other end of the pipe,

A block of weight $100\mathrm{}\mathrm{N}$ is suspended by copper and steel wires of same cross-sectional area $0.5\mathrm{}\mathrm{c}{\mathrm{m}}^2$ and, length $\sqrt{3}\mathrm{}\mathrm{m}$ and $1\mathrm{}\mathrm{m},$ respectively. Their other ends are fixed on a ceiling as shown in figure. The angles subtended by copper and steel wires with ceiling are ${30}^{\mathrm{o}}$ and ${60}^{\mathrm{o}},$ respectively. If elongation in copper wire is $\left(\mathrm{\Delta }{\mathrm{l}}_{\mathrm{C}}\right)$ and elongation in steel wire is $\left(\mathrm{\Delta }{\mathrm{l}}_{\mathrm{S}}\right),$ then the ratio $\frac{\mathrm{\Delta }{\mathrm{l}}_{\mathrm{C}}}{\mathrm{\Delta }{\mathrm{l}}_{\mathrm{S}}}$ is _____.
[Young's modulus for copper and steel are $1\times {10}^{11}\mathrm{N}/{\mathrm{m}}^2$ and $2\times {10}^{11}\mathrm{N}/{\mathrm{m}}^2$ respectively]

The point \(P\) is the intersection of the straight line joining the points \(Q(2,3,5)\) and \(R(1,-1,4)\) with the plane \(5 x-4 y-\) \(z=1\). If \(S\) is the foot of the perpendicular drawn from the point \(T(2,1,4)\) to \(Q R\), then the length of the line segment \(P S\) is