Consider all possible isomeric ketones, including stereoisomers of MW = 100. All these isomers are independently reacted with $\mathrm{N}\mathrm{a}\mathrm{B}{\mathrm{H}}_4$ (NOTE: stereoisomers are also reacted separately). The total number of ketones that give a racemic product(s) is/are

The major product of the following reaction is

According to the Arrhenius equation,

Vessel-1 contains \(\mathbf{w}_2 \mathrm{~g}\) of a non-volatile solute \(\mathbf{X}\) dissolved in \(\mathbf{w}_1 \mathrm{~g}\) of water. Vessel- 2 contains \(\mathbf{w}_2 \mathrm{~g}\) of another non-volatile solute \(\mathbf{Y}\) dissolved in \(\mathbf{w}_1 \mathrm{~g}\) of water. Both the vessels are at the same temperature and pressure. The molar mass of \(\mathbf{X}\) is \(80 \%\) of that of \(\mathbf{Y}\). The van't Hoff factor for \(\mathbf{X}\) is 1.2 times of that of \(\mathbf{Y}\) for their respective concentrations.
The elevation of boiling point for solution in Vessel-1 is ________. \(\%\) of the solution in Vessel-2.

Consider the following list of reagents: Acidified ${\mathrm{K}}_2\mathrm{C}{\mathrm{r}}_2{\mathrm{O}}_7$ , alkaline $\mathrm{K}\mathrm{M}\mathrm{n}{\mathrm{O}}_4,\mathrm{C}\mathrm{u}\mathrm{S}{\mathrm{O}}_4,{\mathrm{H}}_2{\mathrm{O}}_2,\mathrm{C}{\mathrm{l}}_2,{\mathrm{O}}_3,\mathrm{F}\mathrm{e}\mathrm{C}{\mathrm{l}}_3,\mathrm{H}\mathrm{N}{\mathrm{O}}_3$ and $\mathrm{N}{\mathrm{a}}_2{\mathrm{S}}_2{\mathrm{O}}_3$ . The total number of reagents that can oxidise aqueous iodide to iodine is

Among the triatomic molecules/ions, $\mathrm{B}\mathrm{e}\mathrm{C}{\mathrm{l}}_2,\mathrm{ }{\mathrm{N}}_3^{-},\mathrm{ }{\mathrm{N}}_2\mathrm{O},\mathrm{ }{\mathrm{N}\mathrm{O}}_2^{+},\mathrm{ }{\mathrm{O}}_3,\mathrm{S}\mathrm{C}{\mathrm{l}}_2,\mathrm{ }{\mathrm{I}\mathrm{C}\mathrm{l}}_2^{-},\mathrm{ }{\mathrm{I}}_3^{-}$ and $\mathrm{X}\mathrm{e}{\mathrm{F}}_2$ , the total number of linear molecule(s)/ion(s) where the hybridization of the central atom does not have contribution from the d-orbital(s) is
[Atomic number: S = 16, Cl = 17, I = 53 and Xe = 54]

For the following reaction, the equilibrium constant ${\mathrm{K}}_{\mathrm{e}}$ at $298\mathrm{ }\mathrm{K}$ is $1.6\times {10}^{17}.$
$\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)+{\mathrm{S}}^{2-}\left(\mathrm{a}\mathrm{q}\right)\mathrm{ }\rightleftharpoons \mathrm{F}\mathrm{e}\mathrm{S}\left(\mathrm{s}\right)$
When equal volumes of $0.06\mathrm{ }\mathrm{M}\mathrm{ }\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)$ and $0.2\mathrm{ }\mathrm{M}{\mathrm{ }\mathrm{S}}^{2-}\left(\mathrm{a}\mathrm{q}\right)$ solutions are mixed, the equilibrium concentration of $\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)$ is found to be $\mathrm{Y}\times {10}^{-17}\mathrm{M}.$ The value of $\mathrm{Y}$ is __________

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The capacitor of capacitance \(C\) can be charged (with the help of a resistance \(R\) ) by a voltage source \(V\), by closing switch \(S_1\) while keeping switch \(S_2\) open. The capacitor can be connected in series with an inductor \(L\) by closing switch \(S_2\) and opening \(S_1\).

Question :
Initially, the capacitor was uncharged. Now, switch \(S_1\) is closed and \(S_2\) is kept open. If time constant of this circuit is \(\tau\), then

Column I contains a list of processes involving expansion of an ideal gas. Match this with Column II describing the thermodynamic change during this process. Indicate your answer by darkening the appropriate bubbles of the \(4 \times 4\) matrix given in the ORS.

A rod of length $2 \mathrm{cm}$ makes an angle $\frac{2\pi }{3}\mathrm{rad}$ with the principal axis of a thin convex lens. The lens has a focal length of $10 \mathrm{cm}$ and is placed at a distance of $\frac{40}{3} \mathrm{cm}$ from the object as shown in the figure. The height of the image is $\frac{30\sqrt{3}}{13} \mathrm{cm}$ and the angle made by it with respect to the principal axis is \(\alpha\) rad. The value of $\alpha$ is $\frac{\pi }{n}\mathrm{rad}$, where $n$ is

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The reaction of \(\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) with freshly prepared \(\mathrm{FeSO}_{4}\) solution produces a dark blue precipitate called Turnbull's blue. Reaction of \(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) with the \(\mathrm{FeSO}_{4}\) solution in complete absence of air produces a white precipitate \(\mathbf{X}\), which turns blue in air. Mixing the \(\mathrm{FeSO}_{4}\) solution with \(\mathrm{NaNO}_{3}\), followed by a slow addition of concentrated \(\mathrm{H}_{2} \mathrm{SO}_{4}\) through the side of the test tube produces a brown ring.
Question:
Among the following, the brown ring is due to the formation of

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Consider the functions defined implicitly by the equation \(y^3-3 y+x=0\) on various intervals in the real line. If \(x \in(-\infty,-2) \cup(2, \infty)\), the equation implicitly defines a unique real valued differentiable function \(y=f(x)\). If \(x \in(-2,2)\), the equation implicitly defines a unique real valued differentiable function \(y=g(x)\), satisfying \(g(0)=0\).Question:
The area of the region bounded by the curve \(y=f(x)\), the \(X\)-axis and the lines \(x=a\) and \(x=b\), where \(-\infty < a < b < -2\), is

The calculated spin only magnetic moments of ${\left[\mathrm{Cr}{\left({\mathrm{NH}}_3\right)}_6\right]}^{3+}$ and ${\left[{\mathrm{CuF}}_6\right]}^{3-}$ in $\mathrm{BM},$ respectively, are (Atomic numbers of $\mathrm{Cr}$ and $\mathrm{Cu}$ are $24$ and $29,$ respectively)