Among the triatomic molecules/ions, $\mathrm{B}\mathrm{e}\mathrm{C}{\mathrm{l}}_2,\mathrm{ }{\mathrm{N}}_3^{-},\mathrm{ }{\mathrm{N}}_2\mathrm{O},\mathrm{ }{\mathrm{N}\mathrm{O}}_2^{+},\mathrm{ }{\mathrm{O}}_3,\mathrm{S}\mathrm{C}{\mathrm{l}}_2,\mathrm{ }{\mathrm{I}\mathrm{C}\mathrm{l}}_2^{-},\mathrm{ }{\mathrm{I}}_3^{-}$ and $\mathrm{X}\mathrm{e}{\mathrm{F}}_2$ , the total number of linear molecule(s)/ion(s) where the hybridization of the central atom does not have contribution from the d-orbital(s) is
[Atomic number: S = 16, Cl = 17, I = 53 and Xe = 54]

The correct acidity order of the following is

The unbalanced chemical reactions given in List I show missing reagent or condition (?) which are provided in list II. match List I with List II and select the correct answer using the code given below the lists :

List - I	List - II
A. \(PbO _2+ H _2 SO _4 \xrightarrow{?}\) \(PbSO _4 + O _2+\) other product	P. \(\text{NO}\)
B. \(Na _2 S_2 O _3+ H _2 O \xrightarrow{?}\) \(NaHSO _4~+\) other product	Q. \(\text{I}_2\)
C. \(N _2 H _4 \xrightarrow{?} N_2 +\) other product	R. Warm
D. \(XeF _2 \xrightarrow{?} Xe ~+\) other product	S. \(\text{Cl}_2\)

With respect to the compounds$\mathrm{I}-\mathrm{V}$choose the correct statement(s).

For one mole of a van der Waal's gas when \(b=0\) and \(\mathrm{T}=300 \mathrm{~K}\), the PV vs, \(1 / \mathrm{V}\) plot is shown below. The value of the van der Waal's constant \(a\) (atm. liter \({ }^{2} \mathrm{~mol}^{-2}\) ) is :

For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap of two $2{\mathrm{p}}_{\mathrm{z}}$ orbitals is(are)

The electrochemical extraction of aluminium from bauxite ore involves

Let \(\mathbf{a}=-\hat{\mathbf{i}}-\hat{\mathbf{k}}, \mathbf{b}=-\hat{\mathbf{i}}+\hat{\mathbf{j}}\) and \(\mathbf{c}=\hat{\mathbf{i}}+2 \hat{\mathbf{j}}+3 \hat{\mathbf{k}}\) be three given vectors. If \(\mathbf{r}\) is a vector such that \(\mathbf{r} \times \mathbf{b}=\mathbf{c} \times \mathbf{b}\) and \(\mathbf{r} \cdot \mathbf{a}=0\), then the value of \(\mathbf{r} \cdot \mathbf{b}\) is

Match the rate expressions in LIST-I for the decomposition of \(\mathrm{X}\) with the corresponding profiles provided in LIST-II. \(X_s\) and \(\mathrm{k}\) are constants having appropriate units.

Paragraph:
Read the following passage and answer the questions.
Let \(A B C D\) be a square of side length 2 units. \(C_2\) is the circle through vertices \(A, B, C, D\) and \(C_1\) is the circle touching all the sides of square \(A B C D\). \(L\) is the line through \(A\).Question:
A circle touches the line \(L\) and the circle \(C_1\) externally such that both the circles are on the same side of the line, then the locus of centre of the circle is

Let $\overrightarrow{a}, \overrightarrow{b}$ and $\overrightarrow{c}$ be three non - coplanar unit vectors such that the angle between every pair of them is $\frac{\pi }{3}.$ If $\overrightarrow{a} \times \overrightarrow{b}+ \overrightarrow{b} \times \overrightarrow{c}=p\overrightarrow{a}+q\overrightarrow{b}+r\overrightarrow{c}$ , where p, q and r are scalars, then the value of $\frac{p^2+2q^2+r^2}{q^2}$ is _______

A cylindrical vessel of height \(500 \mathrm{~mm}\) has an orifice (small hole) at its bottom. The orifice is initially closed and water is filled in it upto height \(H\). Now the top is completely sealed with a cap and the orifice at the bottom is opened. Some water comes out from the orifice and the water level in the vessel becomes steady with height of water column being 200 \(\mathrm{mm}\). Find the fall in height (in \(\mathrm{mm}\) ) of water level due to opening of the orifice.
[Take atmospheric pressure \(=1.0 \times 10^5 \mathrm{Nm}^{-2}\), density of water \(=1000 \mathrm{~kg} \mathrm{~m}^{-3}\) and \(g=10\) \(\mathrm{ms}^{-2}\). Neglect any effect of surface tension.]

The value of \(b\) for which the equations \(x^2+b x-1=0, x^2+x+b=0\) have one root in common is