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JEE Advanced · Chemistry · 31. Practical Chemistry

Paragraph:
An aqueous solution of metal ion \(\mathbf{M} 1\) reacts separately with reagents \(\mathbf{Q}\) and \(\mathbf{R}\) in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral complexes with these reagents. Aqueous solution of \(\mathbf{M} 2\) on reaction with reagent \(\mathbf{S}\) gives white precipitate which dissolves in excess of \(\mathbf{S}\). The reactions are summarized in the scheme given below:


Question:
\(\mathbf{M} 1, \mathbf{Q}\) and \(\mathbf{R}\), respectively are

  1. A Zn2+, KCN and HCl
  2. B Ni2+, HCl and KCN
  3. C Cd2+, KCN and HCl
  4. D Co2+, HCl and KCN
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Answer & Solution

Correct Answer

(B) Ni2+, HCl and KCN

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