Among ${\mathrm{B}}_2{\mathrm{H}}_6,\mathrm{ }{\mathrm{B}}_3{\mathrm{N}}_3{\mathrm{H}}_6,\mathrm{ }{\mathrm{N}}_2\mathrm{O},\mathrm{ }{\mathrm{N}}_2{\mathrm{O}}_4,\mathrm{ }{\mathrm{H}}_2{\mathrm{S}}_2{\mathrm{O}}_3$ and ${\mathrm{H}}_2{\mathrm{S}}_2{\mathrm{O}}_8,$ the number of molecules containing covalent bond between two atoms of the same kind is __________

The total number(s) of stable conformers with non-zero dipole moment for the following compound is(are)

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Redox reaction play a pivotal role in chemistry and biology. The values of standard redox potential \(\left(E^{\circ}\right)\) of two half-cell reactions decide which way the reaction is expected to proceed. A simple example is a Daniel cell in which zinc goes into solution and copper gets deposited. Given below are a set of half-cell reactions (acidic medium) along with their \(E^{\circ}(V\) with respect to normal hydrogen electrode) values. Using this data obtain the correct explanations to Questions 14-19.
\(\mathrm{I}_2+2 e^{-} \longrightarrow 2 \mathrm{I}^{-} E^{\circ}=0.54 \)
\( \mathrm{Cl}_2+2 e^{-} \longrightarrow 2 \mathrm{Cl}^{-} E^{\circ}=1.36 \)
\( \mathrm{Mn}^{3+}+e^{-} \longrightarrow \mathrm{Mn}^{2+} E^{\circ}=1.50 \)
\( \mathrm{Fe}^{3+}+e^{-} \longrightarrow \mathrm{Fe}^{2+} E^{\circ}=0.77 \)
\( \mathrm{O}_2+4 \mathrm{H}^{+}+4 e^{-} \longrightarrow 2 \mathrm{H}_2 \mathrm{O} E^{\circ}=1.23\)
Question :
Sodium fusion extract, obtained from aniline, on treatment with iron (II) sulphate and \(\mathrm{H}_2 \mathrm{SO}_4\) in presence of air gives a prussian blue precipitate. The blue colour is due to the formation of

For the following reaction, the equilibrium constant ${\mathrm{K}}_{\mathrm{e}}$ at $298\mathrm{ }\mathrm{K}$ is $1.6\times {10}^{17}.$
$\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)+{\mathrm{S}}^{2-}\left(\mathrm{a}\mathrm{q}\right)\mathrm{ }\rightleftharpoons \mathrm{F}\mathrm{e}\mathrm{S}\left(\mathrm{s}\right)$
When equal volumes of $0.06\mathrm{ }\mathrm{M}\mathrm{ }\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)$ and $0.2\mathrm{ }\mathrm{M}{\mathrm{ }\mathrm{S}}^{2-}\left(\mathrm{a}\mathrm{q}\right)$ solutions are mixed, the equilibrium concentration of $\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)$ is found to be $\mathrm{Y}\times {10}^{-17}\mathrm{M}.$ The value of $\mathrm{Y}$ is __________

Match each of the compounds given in Column I with the reaction (s) that they can undergo, given in Column II.

If the distribution of molecular speeds of a gas is as per the figure shown below, then the ratio of the most probable, the average, and the root mean square speeds, respectively, is

Columns 1, 2 and 3 contain starting materials, reaction conditions and type of reactions respectively.

Column 1	Column 2	Column 3
(I) Toulene	(i) \(NaOH\) \( /Br _2\)	(P) Condensation
(II) Acetophenone	(ii) \(B r_2 / h v\)	(Q) Carboxylation
(III) Benzaldehyde	(iii) \(\left( CH _3 CO \right)_2\) \(O / CH _3\) \(COOK\)	(R) Substitution
(IV) Phenol	(iv) \(NaOH\) \(/CO _2\)	(S) Haloform

The only CORRECT combination in which the reaction proceeds through radical mechanism is

In \(1 \mathrm{~L}\) saturated solution of \(\mathrm{AgCl}\left[K_{\mathrm{sp}} \mathrm{AgCl}=1.6 \times 10^{-10}\right], 0.1\) mole of \(\mathrm{CuCl}\left[K_{\mathrm{sp}}(\mathrm{CuCl})=1.0 \times 10^{-6}\right]\) is added. The resultant concentration of \(\mathrm{Ag}^{+}\)in the solution is \(1.6 \times 10^{-x}\). The value of \(x\) is

The function $\mathrm{y}=\mathrm{f}\left(\mathrm{x}\right)$ is the solution of the differential equation $\frac{\mathrm{d}\mathrm{y}}{\mathrm{d}\mathrm{x}}+\frac{\mathrm{x}\mathrm{y}}{{\mathrm{x}}^2-1}=\frac{{\mathrm{x}}^4+2\mathrm{x}}{\sqrt{1-{\mathrm{x}}^2}}$ in (- 1 , 1) satisfying $\mathrm{f}\left(0\right)=0.$ Then $\underset{-\frac{\sqrt{3}}{2}}{\overset{\frac{\sqrt{3}}{2}}{\int }}\mathrm{f}\left(\mathrm{x}\right)\mathrm{ }\mathrm{d}\mathrm{x}$ is

Let $O$ be the center of the circle $x^2+y^2=r^2,$ where $r>\frac{\sqrt{5}}{2}.$ Suppose $PQ$ is a chord of this circle and the equation of the line passing through $P$ and $Q$ is  $2x+4y=5$. If the center of the circumcircle of the triangle $OPQ$ lies on the line $x+2y=4,$ then the value of $r$ is ______

Let \(\mathbb{R}\) denote the set of all real numbers. For a real number \(x\), let \([x]\) denote the greatest integer less than or equal to \(x\). Let \(n\) denote a natural number.
Match each entry in List-I to the correct entry in List-II and choose the correct option.

	LIST - I		LIST - II
(P)	The minimum value of \(n\) for which the function \(f(x)=\left[\frac{10 x^3-45 x^2+60 x+35}{n}\right]\) is continuous on the interval \([1,2]\),is	(1)	8
(Q)	The minimum value of \(n\) for which \(g(x)=\left(2 n^2-13 n-15\right)\left(x^3+3 x\right),x \in \mathbb{R}\),is an increasing function on \(\mathbb{R}\),is	(2)	9
(R)	The smallest natural number \(n\) which is greater than 5,such that \(x=3\) is a point of local minima of \(h(x)=\left(x^2-9\right)^{\mathrm{n}}\left(x^2+2 x+3\right)\),is	(3)	5
(S)	Number of \(x_0 \in \mathbb{R}\) such that \(l(x)=\sum_{k=0}^4\left(\sin |x-k|+\cos \left|x-k+\frac{1}{2}\right|\right),x \in \mathbb{R}\),is NOT differentiable at \(x_0\),is	(4)	6
		(5)	10

Two bars of radius ' \(r\) ' and ' \(2 r\) ' are kept in contact as shown. An electric current \(I\) is passed through the bars. Which one of the following is correct?

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Consider a simple \(R C\) circuit as shown in Figure \(1\).

Process 1: In the circuit the switch \(S\) is closed at \(t=0\) and the capacitor is fully charged to voltage \(V_{0}\) (i.e., charging continues for time \(T>>R C\) ). In the process some dissipation \(\left(E_{D}\right)\) occurs across the resistance \(R\). The amount of energy finally stored in the fully charged capacitor is \(E_{C}\).

Process 2: In a different process the voltage is first set to \(\frac{V_{0}}{3}\) and maintained for a charging time \(T>>R C\). Then the voltage is raised to \(\frac{2 V_{0}}{3}\) without discharging the capacitor and again maintained for a time \(T>>R C\). The process is repeated one more time by raising the voltage to \(V_{0}\) and the capacitor is charged to the same final voltage \(V_{0}\) as in Process 1.

These two processes are depicted in Figure \(2 .\)







Question:

In Process 2, total energy dissipated across the resistance \(E_{D}\) is: