Columns 1, 2 and 3 contain starting materials, reaction conditions and type of reactions respectively.

Column 1	Column 2	Column 3
(I) Toulene	(i) \(NaOH\) \( /Br _2\)	(P) Condensation
(II) Acetophenone	(ii) \(B r_2 / h v\)	(Q) Carboxylation
(III) Benzaldehyde	(iii) \(\left( CH _3 CO \right)_2\) \(O / CH _3\) \(COOK\)	(R) Substitution
(IV) Phenol	(iv) \(NaOH\) \(/CO _2\)	(S) Haloform

The only CORRECT combination in which the reaction proceeds through radical mechanism is

The plot of ${\mathrm{logk}}_{\mathrm{f}}$ versus $\frac{1}{\mathrm{T}}$ for a reversible reaction $\mathrm{A}\left(\mathrm{g}\right)\rightleftharpoons \mathrm{P}\left(\mathrm{g}\right)$ is shown.

Pre-exponential factors for the forward and backward reactions are ${10}^{15} {\mathrm{s}}^{-1}$ and ${10}^{11} {\mathrm{s}}^{-1}$, respectively. If the value of $\mathrm{logK}$ for the reaction at $500 \mathrm{K}$ is $6$, the value of $\left|{\mathrm{logk}}_{\mathrm{b}}\right|$ at $250 \mathrm{K}$ is
$\left[\mathrm{K}=\right.$equilibrium constant of the reaction, ${\mathrm{k}}_{\mathrm{f}}=$rate constant of forward reaction, ${\mathrm{K}}_{\mathrm{b}}=$rate constant of backward reaction]

The compound (s) having peroxide linkage is(are) :

Match the chemical substance in Column I with type of polymers/type of bonds in Column II. Indicate your answer by darkening the appropriate bubbles of the \(4 \times 4\) matrix given in the ORS.

Column I	Column II
A. \(C _6 H _5 CHO\)	p. Gives precipitate with 2, 4-dinitrophenylhydrazine
B. \(CH _3 \equiv CH\)	q. Gives precipitate with \(AgNO _3\)
C. \(CN ^{-}\)	r. Is a nucleophile
D. \(I ^{-}\)	s. Is involved in cyanohydrin formation

For the reaction sequence given below, the correct statement(s) is(are)

The correct statement(s) regarding defects in solids is (are)

Solubility product constant \(\left(K_{\mathrm{sp}}\right)\) of salts of types \(M X, M X_2\) and \(M_3 X\) at temperature ' \(T\) ' are \(4.0 \times 10^{-8}, 3.2 \times 10^{-14}\) and \(2.7 \times 10^{-15}\), respectively. Solubilities \(\left(\mathrm{mol} \mathrm{dm}^{-3}\right)\) of the salts at temperature ' \(T\) ' are in the order

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Let \(f:[0,1] \rightarrow \mathbb{R}\) (the set of all real numbers) be a function. Suppose the function \(f\) is twice differentiable, \(f(0)=f(1)=0\) and satisfies \(f^{\prime \prime}(x)-2 f^{\prime}(x)+f(x) \geq e^{x}, x \in[0,1] .\)


Question:

Which of the following is true for \(f(x)\) ?

Total number of cis $\mathrm{N}-\mathrm{M}\mathrm{n}-\mathrm{C}\mathrm{l}$ bond angles (that is, $\mathrm{M}\mathrm{n}-\mathrm{N}$ and $\mathrm{M}\mathrm{n}-\mathrm{C}\mathrm{l}$ bonds in cis positions) present in a molecule of cis- $\left[\mathrm{M}\mathrm{n}{\left(\mathrm{e}\mathrm{n}\right)}_2{\mathrm{C}\mathrm{l}}_2\right]$ complex is _________ $\left(en={\mathrm{N}\mathrm{H}}_2{\mathrm{C}\mathrm{H}}_2{\mathrm{C}\mathrm{H}}_2{\mathrm{N}\mathrm{H}}_2\right)$

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A frame of reference that is accelerated with respect to an inertial frame of reference is called a non-inertial frame of reference. A coordinate system fixed on a circular disc rotating about a fixed axis with a constant angular velocity \(\omega\) is an example of a non-inertial frame of reference.

The relationship between the force \(\vec{F}_{\text {rot }}\) experienced by a particle of mass \(m\) moving on the rotating disc and the force \(\vec{F}_{\text {in }}\) experienced by the particle in an inertial frame of reference is

\(\vec{F}_{\mathrm{rot}}=\vec{F}_{\mathrm{in}}+2 m\left(\vec{v}_{\mathrm{rot}} \times \vec{\omega}\right)+m(\vec{\omega} \times \vec{r}) \times \vec{\omega}\),

where \(\vec{v}_{\text {rot }}\) is the velocity of the particle in the rotating frame of reference and \(\vec{r}\) is the position vector of the particle with respect to the centre of the disc.

Now consider a smooth slot along a diameter of a disc of radius \(R\) rotating counter-clockwise with a constant angular speed \(\omega\) about its vertical axis through its center. We assign a coordinate system with the origin at the center of the disc, the \(x\)-axis along the slot, the \(y\)-axis perpendicular to the slot and the \(z\)-axis along the rotation axis \((\vec{\omega}=\omega \hat{k}) .\) A small block of mass \(m\) is gently placed in the slot at \(\vec{r}=(R / 2) \hat{i}\) at \(t=0\) and is constrained to move only along the slot.


Question:
The distance \(r\) of the block at time \(t\) is

When two identical batteries of internal resistance \(1 \Omega\) each are connected in series across a resistor \(R\), the rate of heat produced in \(R\) is \(J_1\). When the same batteries are connected in parallel across \(R\), the rate is \(J_2\). If \(J_1=2.25 J_2\) then the value of \(R\) in \(\Omega\) is

The correct option(s) related to adsorption processes is(are)

A single slit diffraction experiment is performed to determine the slit width using the equation, \(\frac{b d}{D}=m \lambda\), where \(b\) is the slit width, \(D\) the shortest distance between the slit and the screen, \(d\) the distance between the \(m^{\text {th }}\) diffraction maximum and the central maximum, and \(\lambda\) is the wavelength. \(D\) and \(d\) are measured with scales of least count of 1 cm and 1 mm, respectively. The values of \(\lambda\) and \(m\) are known precisely to be 600 nm and 3, respectively. The maximum absolute error (in \(\mu \mathrm{m}\)) in the value of \(b\) estimated using the diffraction maximum that occurs for \(m=3\) with \(d=5 \mathrm{~mm}\) and \(D=1 \mathrm{~m}\) is ______.