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WBJEE · Chemistry · s Block Elements

In the extraction of Ca by electro reduction of molten \(\mathrm{CaCl}_{2}\) some \(\mathrm{CaF}_{2}\) is added to the electrolyte for the following reason:

  1. A To keep the electrolyte in liquid state at temperature lower than the m. p. of \(\mathrm{CaCl}_{2}\)
  2. B To effect precipitation of Ca
  3. C To effect the electrolysis at lower voltage
  4. D To increase the current efficiency
Verified Solution

Answer & Solution

Correct Answer

(A) To keep the electrolyte in liquid state at temperature lower than the m. p. of \(\mathrm{CaCl}_{2}\)

Step-by-step Solution

Detailed explanation

Hint: \(\mathrm{CaF}_{2}\) decreases the melting point of \(\mathrm{CaCl}_{2}\)
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