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WBJEE · Chemistry · General Principles and Processes of Isolation of Metals

In aluminium extraction by the Bayer process, alumina is extracted from bauxite by sodium hydroxide at high temperature and pressures :
\(\mathrm{Al}_2 \mathrm{O}_3(\mathrm{~s})+2 \mathrm{OH}^{-}(\mathrm{aq}) \rightarrow 2 \mathrm{Al}_2 \mathrm{O}_2(\mathrm{aq})+\mathrm{H}_2 \mathrm{O}(1)\)

Solid impurities such as \(\mathrm{Fe}_2 \mathrm{O}_3\) and \(\mathrm{SiO}_2\) are removed and then \(\mathrm{Al}(\mathrm{OH})_4^{-}\)is reprecipitated : \(2 \mathrm{Al}(\mathrm{OH})_4^{-} \rightarrow \mathrm{Al}_2 \mathrm{O}_3 \cdot 3 \mathrm{H}_2 \mathrm{O}(\mathrm{s})+2 \mathrm{OH}^{-}\)(aq) . In the industrial world :

  1. A Carbon dioxide is added to precipitate the alumina
  2. B Temperature and pressure are dropped and the supersaturated solution seeded
  3. C Both (1) and (2) are practised
  4. D The water is evaporated
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(B) Temperature and pressure are dropped and the supersaturated solution seeded

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