TS EAMCET · Chemistry · Coordination Compounds
The reaction of aqueous Is performed by the addition of a bidentate ligand ethane-1, 2, diamine (en)
Match the following
| en molar ratio | Colour of the product | ||
| A | I | Pale blue | |
| B | II | Blue / Purple | |
| C | III | Violet | |
| D | IV | Green |
- A
A B C I II III - B
A B C II III IV - C
.A B C III I II - D
A B C IV I III
Answer & Solution
Correct Answer
(A)
A B C I II III
Step-by-step Solution
Detailed explanation
According to the question, in case of [MX6], M=Ni, X= weak field ligand or strong field ligand, Nickel is always forms sp3d2 Hybridisation. Ni+2=3d8,4s0. In this condition Nickel has two -unpair electrons. Due to this it shows green colour.
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