KCET · Chemistry · Aldehydes and Ketones
Match the reagents in List-I with products obtained from their carbonyl compounds in List-II.
| List-I | List-II | ||
|---|---|---|---|
| (a) | \(\text{NH}_2\text{OH}\) | (i) | Cyanohydrin |
| (b) | \(R-\text{NH}_2\) | (ii) | Oxime |
| (c) | \(R-\text{OH}\) | (iii) | Schiff base |
| (d) | \(H-C \equiv N\) | (iv) | Acetal |
- A a-ii, b-iii, c-iv, d-i
- B a-i, b-ii, c-iii, d-iv
- C a-iii, b-ii, c-i, d-iv
- D a-i, b-iii, c-ii, d-iv
Answer & Solution
Correct Answer
(A) a-ii, b-iii, c-iv, d-i
Step-by-step Solution
Detailed explanation
Reaction of carbonyl compounds with various reagents yields specific products:
(a) Reaction with hydroxylamine (\(\text{NH}_2\text{OH}\)) forms an oxime.
\(\text{C=O} + \text{NH}_2\text{OH} \rightarrow \text{C=N-OH} + \text{H}_2\text{O}\)
(b) Reaction with a primary amine (\(R-\text{NH}_2\)) forms a substituted imine, also known as a Schiff base.
\(\text{C=O} + R-\text{NH}_2 \rightarrow \text{C=N}-R + \text{H}_2\text{O}\)
(c) Reaction with an alcohol (\(R-\text{OH}\)) in the presence of dry HCl gas forms a hemiacetal, which further reacts with another molecule of alcohol to form an acetal.
\(\text{RCHO} + 2R'\text{OH} \rightarrow \text{RCH(OR')}_2 + \text{H}_2\text{O}\)
(d) Reaction with hydrogen cyanide (\(\text{HCN}\)) forms a cyanohydrin.
\(\text{C=O} + \text{HCN} \rightarrow \text{C(OH)(CN)}\)
Thus, the correct matching is (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i).
Answer: a-ii, b-iii, c-iv, d-i
(a) Reaction with hydroxylamine (\(\text{NH}_2\text{OH}\)) forms an oxime.
\(\text{C=O} + \text{NH}_2\text{OH} \rightarrow \text{C=N-OH} + \text{H}_2\text{O}\)
(b) Reaction with a primary amine (\(R-\text{NH}_2\)) forms a substituted imine, also known as a Schiff base.
\(\text{C=O} + R-\text{NH}_2 \rightarrow \text{C=N}-R + \text{H}_2\text{O}\)
(c) Reaction with an alcohol (\(R-\text{OH}\)) in the presence of dry HCl gas forms a hemiacetal, which further reacts with another molecule of alcohol to form an acetal.
\(\text{RCHO} + 2R'\text{OH} \rightarrow \text{RCH(OR')}_2 + \text{H}_2\text{O}\)
(d) Reaction with hydrogen cyanide (\(\text{HCN}\)) forms a cyanohydrin.
\(\text{C=O} + \text{HCN} \rightarrow \text{C(OH)(CN)}\)
Thus, the correct matching is (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i).
Answer: a-ii, b-iii, c-iv, d-i
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