KCET · Chemistry · Classification of Elements and Periodicity in Properties
Match List-I with List-II:
| List-I (Element-Atomic number) | List-II (Position in periodic table) | ||
|---|---|---|---|
| (a) | Ra – 88 | (i) | \(4^{th}\) period, \(13^{th}\) group |
| (b) | Ga – 31 | (ii) | \(6^{th}\) period, \(6^{th}\) group |
| (c) | W – 74 | (iii) | \(5^{th}\) period, \(10^{th}\) group |
| (d) | Pd – 46 | (iv) | \(7^{th}\) period, \(2^{nd}\) group |
- A a-iv, b-i, c-ii, d–iii
- B a-i, b-ii, c-iii, d-iv
- C a-iv, b-ii, c-iii, d–i
- D a-iii, b-iv, c-i, d-ii
Answer & Solution
Correct Answer
(A) a-iv, b-i, c-ii, d–iii
Step-by-step Solution
Detailed explanation
The position of an element in the periodic table can be determined using its atomic number and the nearest preceding noble gas.
(a) Ra (\(Z = 88\)): The preceding noble gas is Radon (Rn, \(Z = 86\)), which belongs to the \(6^{th}\) period and \(18^{th}\) group. The next two electrons enter the \(7s\) orbital. Thus, Ra belongs to the \(7^{th}\) period and \(2^{nd}\) group. (a) \(\rightarrow\) (iv)
(b) Ga (\(Z = 31\)): The preceding noble gas is Argon (Ar, \(Z = 18\)), which belongs to the \(3^{rd}\) period. The next electrons fill the \(4s\), \(3d\), and \(4p\) orbitals. The group number is \(31 - 18 = 13\). Thus, Ga belongs to the \(4^{th}\) period and \(13^{th}\) group. (b) \(\rightarrow\) (i)
(c) W (\(Z = 74\)): The preceding noble gas is Xenon (Xe, \(Z = 54\)), which belongs to the \(5^{th}\) period. The next electrons fill the \(6s\), \(4f\) (14 elements), and \(5d\) orbitals. The group number is \(74 - 54 - 14 = 6\). Thus, W belongs to the \(6^{th}\) period and \(6^{th}\) group. (c) \(\rightarrow\) (ii)
(d) Pd (\(Z = 46\)): The preceding noble gas is Krypton (Kr, \(Z = 36\)), which belongs to the \(4^{th}\) period. The next electrons fill the \(5s\) and \(4d\) orbitals. The group number is \(46 - 36 = 10\). Thus, Pd belongs to the \(5^{th}\) period and \(10^{th}\) group. (d) \(\rightarrow\) (iii)
The correct matching is a-iv, b-i, c-ii, d-iii.
Answer: a-iv, b-i, c-ii, d–iii
(a) Ra (\(Z = 88\)): The preceding noble gas is Radon (Rn, \(Z = 86\)), which belongs to the \(6^{th}\) period and \(18^{th}\) group. The next two electrons enter the \(7s\) orbital. Thus, Ra belongs to the \(7^{th}\) period and \(2^{nd}\) group. (a) \(\rightarrow\) (iv)
(b) Ga (\(Z = 31\)): The preceding noble gas is Argon (Ar, \(Z = 18\)), which belongs to the \(3^{rd}\) period. The next electrons fill the \(4s\), \(3d\), and \(4p\) orbitals. The group number is \(31 - 18 = 13\). Thus, Ga belongs to the \(4^{th}\) period and \(13^{th}\) group. (b) \(\rightarrow\) (i)
(c) W (\(Z = 74\)): The preceding noble gas is Xenon (Xe, \(Z = 54\)), which belongs to the \(5^{th}\) period. The next electrons fill the \(6s\), \(4f\) (14 elements), and \(5d\) orbitals. The group number is \(74 - 54 - 14 = 6\). Thus, W belongs to the \(6^{th}\) period and \(6^{th}\) group. (c) \(\rightarrow\) (ii)
(d) Pd (\(Z = 46\)): The preceding noble gas is Krypton (Kr, \(Z = 36\)), which belongs to the \(4^{th}\) period. The next electrons fill the \(5s\) and \(4d\) orbitals. The group number is \(46 - 36 = 10\). Thus, Pd belongs to the \(5^{th}\) period and \(10^{th}\) group. (d) \(\rightarrow\) (iii)
The correct matching is a-iv, b-i, c-ii, d-iii.
Answer: a-iv, b-i, c-ii, d–iii
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