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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Match the LIST-I with LIST-II
LIST-I (Molecules/ion)LIST-II (Hybridisation of central atom)
A. \(PF _5\)I. \(dsp ^2\)
B. \(SF _6\)II. \(sp ^3 d\)
C. \(Ni ( CO )_4\)III. \(sp ^3 d^2\)
D. \(\left[ PtCl _4\right]^{2-}\)IV. \(sp ^3\)

Choose the correct answer from the options given below

  1. A A-II, B-III, C-IV, D-I
  2. B A-IV, B-I, C-II, D-III
  3. C A-I, B-II, C-III, D-IV
  4. D A-III, B-I, C-IV, D-II
Verified Solution

Answer & Solution

Correct Answer

(A) A-II, B-III, C-IV, D-I

Step-by-step Solution

Detailed explanation

\(\begin{aligned} & \mathrm{PF}_5: 5 \sigma+0 \ell \mathrm{p} \rightarrow \mathrm{sp}^3 \mathrm{~d} \\ & \mathrm{SF}_6: 6 \sigma+0 \ell \mathrm{p} \rightarrow \mathrm{sp}^3 \mathrm{~d}^2 \\ & \mathrm{Ni}(\mathrm{CO})_4: \mathrm{Ni} \rightarrow 0 \end{aligned}\) In presence of…
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