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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Which of the following complexes will show coordination isomerism?
A. \([Ag(NH_3)_2][Ag(CN)_2]\)
B. \([Co(NH_3)_6][Cr(CN)_6]\)
C. \([Co(NH_3)_6][Co(CN)_6]\)
D. \([Fe(NH_3)_6][Co(CN)_6]\)
E. \([Co(NH_3)_6][Fe(CN)_6]\)
Choose the correct answer from the options given below:

  1. A B, C and D Only
  2. B B, D and E Only
  3. C A, C and D Only
  4. D C, D and E Only
Verified Solution

Answer & Solution

Correct Answer

(B) B, D and E Only

Step-by-step Solution

Detailed explanation

Coordination isomerism arises from the interchange of ligands between cationic and anionic entities of different metal ions present in a complex. A. \([Ag(NH_3)_2][Ag(CN)_2]\): Both the complex cation and anion contain the same metal ion (\(Ag^+\)). Interchanging one ligand…
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