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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

When \(\Delta \mathrm{H}_{\mathrm{vap}}=30 \mathrm{~kJ} / \mathrm{mol}\) and \(\Delta \mathrm{S}_{\mathrm{vap}}=75 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}\), then the temperature of vapour, at one atmosphere is _______ \(\mathrm{K}\).

  1. A \(500\)
  2. B \(400\)
  3. C \(120\)
  4. D \(654\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(400\)

Step-by-step Solution

Detailed explanation

At equilibrium \(\Delta \mathrm{G}_{\mathrm{PT}}=0\) \( \Delta \mathrm{H}_{\text {vap }}=\mathrm{T} \Delta \mathrm{S}_{\text {vap }} \) \( 30 \times 1000=\mathrm{T} \times 75 \) \( \mathrm{~T}=400 \mathrm{~K}\)
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