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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

The incorrect relationship in the following pairs in relation to ionisation enthalpies is _______.

  1. A \(\mathrm{Mn}^{+} \lt \mathrm{Cr}^{+}\)
  2. B \(\mathrm{Mn}^{+} \lt \mathrm{Mn}^{2+}\)
  3. C \(\mathrm{Fe}^{2+} \lt \mathrm{Fe}^{3+}\)
  4. D \(\mathrm{Mn}^{2+} \lt \mathrm{Fe}^{2+}\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(\mathrm{Mn}^{2+} \lt \mathrm{Fe}^{2+}\)

Step-by-step Solution

Detailed explanation

\(\mathrm{Mn}^{2+}:[\mathrm{Ar}] 3 \mathrm{~d}^5\) Half filled stability More 1 E than \(\mathrm{Fe}^{2+}\) \(\mathrm{Fe}^{2+}:[\mathrm{Ar}] 3 \mathrm{~d}^6\)
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