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JEE Mains · Chemistry · STD 12 - 9. Amines

Identify correct statements :
(A) Primary amines do not give diazonium salts when treated with \(\mathrm{NaNO}_2\) in acidic condition.
(B) Aliphatic and aromatic primary amines on heating with \(\mathrm{CHCl}_3\) and ethanolic KOH form carbylamines.
(C) Secondary and tertiary amines also give carbylamine test.
(D) Benzenesulfonyl chloride is known as Hinsberg's reagent.
(E) Tertiary amines reacts with benzenesulfonyl chloride very easily.

Choose the correct answer from the options given below :

  1. A (A) and (B) only
  2. B (D) and (E) only
  3. C (B) and (D) only
  4. D (B) and (C) only
Verified Solution

Answer & Solution

Correct Answer

(C) (B) and (D) only

Step-by-step Solution

Detailed explanation

(C) Only primary amine gives carbyl amine test (D) Benzene sulphonyl chloride \(\mathrm{Ph}-\mathrm{SO}_2 \mathrm{Cl}\) \(\qquad\) Hinsberg reagent (E) Tertiary amine do not react with \(\mathrm{Ph}-\mathrm{SO}_2 \mathrm{Cl}\) So correct options are (B) and (D) only
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