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JEE Mains · Chemistry · STD 12 -1. Solution and colligative properties

The elevation in boiling point for \(1\) molal solution of non-volatile solute \(A\) is \(3\,K\). The depression in freezing point for \(2\) molal solution of \(A\) in the same solvent is \(6\,K\). The ratio of \(K _{ b }\) and \(K _{ f }\) i.e., \(K _{ b } / K _{ f }\) is \(1: X\). The value of \(X\) is [nearest integer]

  1. A \(0\)
  2. B \(1\)
  3. C \(2\)
  4. D \(3\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(1\)

Step-by-step Solution

Detailed explanation

\(\Delta T _{ b }= iK _{ b } m _{1} \quad \Delta T _{ f }= iK _{ f } m _{2}\) \(\frac{\Delta T _{ b }}{\Delta T _{ f }}=\frac{ K _{ b } \times 1}{ K _{ f } \times 2}\) \(\Rightarrow \frac{3}{6}=\frac{1}{2}=\frac{ K _{ b }}{ K _{ f }} \times \frac{1}{2}\)…
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