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JEE Mains · Chemistry · STD 12 - 2. Electrochemistry

In an electrochemical reaction of lead, at standard temperature, if \(E _{\left( Pb ^{2+} / Pb \right)}^0= m\) Volt and \(E _{\left( Pb ^{4+} / Pb \right)}^0= n\) Volt, then the value of \(E _{\left( Pb ^{2+} / Pb ^{4+}\right)}^0\) is given by \(m-x n\). The value of \(x\) is \(...........\). (Nearest integer)

  1. A \(4\)
  2. B \(6\)
  3. C \(8\)
  4. D \(2\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(2\)

Step-by-step Solution

Detailed explanation

\(Pb ^{2+}+2 e ^{-} \rightarrow Pb \quad \Delta G _1^0=-2 FE _1^0\) \(Pb ^{4+}+4 e ^{-} \rightarrow Pb \quad \Delta G _2^0=-4 FE _2^0\) \(Pb ^{2+} \rightarrow Pb ^{4+}+2 e ^{-} \quad \Delta G _3^0=-2 FE _3^0\) \(\Delta G _3^0=\Delta G _1^0-\Delta G _2^0\)…