JEE Mains · Chemistry · STD 12 - 2. Electrochemistry
In an electrochemical reaction of lead, at standard temperature, if \(E _{\left( Pb ^{2+} / Pb \right)}^0= m\) Volt and \(E _{\left( Pb ^{4+} / Pb \right)}^0= n\) Volt, then the value of \(E _{\left( Pb ^{2+} / Pb ^{4+}\right)}^0\) is given by \(m-x n\). The value of \(x\) is \(...........\). (Nearest integer)
- A \(4\)
- B \(6\)
- C \(8\)
- D \(2\)
Answer & Solution
Correct Answer
(D) \(2\)
Step-by-step Solution
Detailed explanation
\(Pb ^{2+}+2 e ^{-} \rightarrow Pb \quad \Delta G _1^0=-2 FE _1^0\) \(Pb ^{4+}+4 e ^{-} \rightarrow Pb \quad \Delta G _2^0=-4 FE _2^0\) \(Pb ^{2+} \rightarrow Pb ^{4+}+2 e ^{-} \quad \Delta G _3^0=-2 FE _3^0\) \(\Delta G _3^0=\Delta G _1^0-\Delta G _2^0\)…
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- The equivalent conductance of \(NaCl \) at concentration \(C\) and at infinite dilution are \(\lambda _C\) and \(\lambda _{\infty}\) respectively. The correct relationship between \(\lambda _C\) and \(\lambda _{\infty}\) is given as : (Where the constant \(B\) is positive)JEE Mains 2014 Hard
- Given below are two statements :
Statement I : A homolepitc octahedral complex, formed using monodentate ligands, will not show stereoisomerism.
Statement II : cis- and trans- platin are heteroleptic complexes of Pd.
In the light of the above statements, choose the correct answer from the options given below.JEE Mains 2025 Medium - Which of the following is not formed when \(H_2S\) reacts with acidic \(K_2Cr_2O_7\) solution ?JEE Mains 2014 Medium
- Among the following compounds, the increasing order of their basic strength is
JEE Mains 2017 Hard - Benzyl isocyanide can be obtained from

Choose the correct answer from the options given below:JEE Mains 2026 Medium - A compound ' \(X\) ' when treated with phthalic anhydride in presence of concentrated \(H _2 SO _4\) yields ' \(Y\) '. ' \(Y\) ' is used as an acid/base indicator. ' \(X\) ' and ' \(Y\) ' are respectively:JEE Mains 2023 Medium
More PYQs from JEE Mains
- If \(a=\lim _{n \rightarrow \infty} \sum_{k=1}^{n} \frac{2 n}{n^{2}+k^{2}}\) and \(f(x)=\) \(\sqrt{\frac{1-\cos x}{1+\cos x}}, x \in(0,1)\), then.JEE Mains 2022 Hard
- Let \(s _1, s _2, s _3, \ldots \ldots, s _{10}\) respectively be the sum to 12 terms of 10 A.P.s whose first terms are \(1,2,3, \ldots, 10\) and the common differences are \(1,3,5, \ldots, 19\) respectively. Then \(\sum \limits_{i=1}^{10} s _{ i }\) is equal toJEE Mains 2023 Hard
- Electromagnetic radiation of wavelength \(663\,nm\) is just sufficient to ionise the atom of metal \(A.\) The ionization energy of metal \(A\) in \(kJ\, mol ^{-1}\) is ...... . (Rounded-off to the nearest integer) \(\left[ h =6.63 \times 10^{-34}\, Js , c =3.00 \times 10^{8} \,ms ^{-1}\right.\) \(,\) \(\left. N _{ A }=6.02 \times 10^{23}\, mol ^{-1}\right]\)JEE Mains 2021 Medium
- Lines are drawn parallel to the line \(4x -3y + 2 = 0\) at a distance \(\frac {3}{5}\) from the origin. Then which one of the following points lies on any of these lines?JEE Mains 2019 Hard
- If a circle \(C\) passing through the point \((4, 0)\) touches the circle \(x^2 + y^2 + 4x -6y = 12\) externally at the point \((1, -1)\), then the radius of \(C\) isJEE Mains 2019 Hard
- \(4 \int_0^1\left(\frac{1}{\sqrt{3+x^2}+\sqrt{1+x^2}}\right) d x-3 \log _e(\sqrt{3})\) is equal to :JEE Mains 2025 Medium