JEE Mains · Chemistry · STD 11 - 4. Chemical bonding and molecular structure
Given below are two statements:
Statement (I) : for \(\mathrm{ClF}_3\), all three possible structures may be drawn as follows.

Statement (II) : Structure III is most stable, as the orbitals having the lone pairs are axial, where the \(\ell \mathrm{p}-\mathrm{bp}\) repulsion is minimum.
In the light of the above statements, choose the most appropriate answer from the options given below:
- A Statement I is incorrect but statement II is correct.
- B Statement I is correct but statement II is incorrect.
- C Both Statement I and statement II are correct.
- D Both Statement I and statement II are incorrect.
Answer & Solution
Correct Answer
(B) Statement I is correct but statement II is incorrect.
Step-by-step Solution
Detailed explanation
Statement 1 is correct. Statement 2 is incorrect since in \(\mathrm{sp}^3 \mathrm{~d}\) hybridization; lone pair cannot occupy axial position.
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