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JEE Mains · Chemistry · STD 11 - 4. Chemical bonding and molecular structure

Given below are two statements:
Statement (I) : for \(\mathrm{ClF}_3\), all three possible structures may be drawn as follows.

Statement (II) : Structure III is most stable, as the orbitals having the lone pairs are axial, where the \(\ell \mathrm{p}-\mathrm{bp}\) repulsion is minimum.
In the light of the above statements, choose the most appropriate answer from the options given below:

  1. A Statement I is incorrect but statement II is correct.
  2. B Statement I is correct but statement II is incorrect.
  3. C Both Statement I and statement II are correct.
  4. D Both Statement I and statement II are incorrect.
Verified Solution

Answer & Solution

Correct Answer

(B) Statement I is correct but statement II is incorrect.

Step-by-step Solution

Detailed explanation

Statement 1 is correct. Statement 2 is incorrect since in \(\mathrm{sp}^3 \mathrm{~d}\) hybridization; lone pair cannot occupy axial position.
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