JEE Mains · Chemistry · STD 12 - 9. Amines
Given below are two statements: Statement \(I :\) Aniline is less basic than acetamide. Statement \(II :\) In aniline, the lone pair of electrons on nitrogen atom is delocalised over benzene ring due to resonance and hence less available to a proton. Choose the most appropriate option:
- A Both statement \(I\) and statement \(II\) are true.
- B Both statement \(I\) and statement \(II\) are false.
- C Statement \(\mathrm{I}\) is true but statement \(II\) is false.
- D Statement \(\mathrm{I}\) is false but statement \(II\) is true.
Answer & Solution
Correct Answer
(D) Statement \(\mathrm{I}\) is false but statement \(II\) is true.
Step-by-step Solution
Detailed explanation
Explanation :- aniline is more basic than acetamide because in acetamide, lone pair of nitrogen is delocalized to more electronegative element oxygen. In Aniline lone pair of nitrogen delocalised over benzene ring.
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