Considering acetic acid dissociates in water, its dissociation constant is \(6.25 \times 10^{-5}\). If \(5 \mathrm{~mL}\) of acetic acid is dissolved in \(1\) litre water, the solution will freeze at \(-\mathrm{x} \times 10^{-2}{ }^{\circ} \mathrm{C}\), provided pure water freezes at \(0^{\circ} \mathrm{C}\). \(\mathrm{x}=\) _______ (Nearest integer) Given : \(\left(\mathrm{K}_{\mathrm{r}}\right)_{\text {water }}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\). density of acetic acid is \(1.2 \mathrm{~g} \mathrm{~mol}^{-1}\) molar mass of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\). molar mass of acetic acid \(=60 \mathrm{~g} \mathrm{~mol}^{-1}\). density of water \(=1 \mathrm{~g} \mathrm{~cm}^{-3}\) Acetic acid dissociates as \(\mathrm{CH}_3 \mathrm{COOH} \rightleftharpoons \mathrm{CH}_3 \mathrm{COO}^{\oplus}+\mathrm{H}^{\oplus}\)

1. A \(19\)
2. B \(20\)
3. C \(25\)
4. D \(30\)