JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Among \((a) - (d)\) the complexes that can display geometrical isomerism are \((a)\) \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}\right]^{+}\) \((b)\) \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right) \mathrm{Cl}_{5}\right]^{-}\) \((c)\) \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}\left(\mathrm{NO}_{2}\right)\right]\) \((d)\) \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{ClBr}\right]^{2+}\)
- A \((d)\) and \((a)\)
- B \((a)\) and \((b)\)
- C \((b)\) and \((c)\)
- D \((c)\) and \((d)\)
Answer & Solution
Correct Answer
(D) \((c)\) and \((d)\)
Step-by-step Solution
Detailed explanation
\(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}\right]^{+}\) and \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right) \mathrm{Cl}_{5}\right]^{-}\) does not show geometrical isomerism
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