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JEE Mains · Chemistry · STD 12 - 3. Chemical kinetics

\(2 NO ( g )+ Cl _{2}( g ) \rightleftharpoons 2 NOCl ( s )\) This reaction was studied at \(-10^{\circ} C\) and the following data was obtained
run \([ NO ]_{0}\) \(\left[ Cl _{2}\right]_{0}\) \(r _{0}\)
\(1\) \(0.10\) \(0.10\) \(0.18\)
\(2\) \(0.10\) \(0.20\) \(0.35\)
\(3\) \(0.20\) \(0.20\) \(1.40\)
\([ NO ]_{0}\) and \(\left[ Cl _{2}\right]_{0}\) are the initial concentrations and \(r _{0}\) is the initial reaction rate. The overall order of the reaction is .......... (Round off to the Nearest Integer).

  1. A \(1\)
  2. B \(2\)
  3. C \(3\)
  4. D \(4\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(3\)

Step-by-step Solution

Detailed explanation

\(r = k [ NO ]^{ m }\left[ Cl _{2}\right]^{ n }\) \(= k (0.1)^{ m }(0.1)^{ n } \quad \ldots . .(1)\) \(= k (0.1)^{ m }(0.2)^{ n } \quad \ldots . .(2)\) \(= k (0.2)^{ m }(0.2)^{ n } \ldots \ldots(3)\) \(n =1\) \(m =2\) \(m + n =3\)
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