For positive integer $n$, define $f\left(n\right)=n+\frac{16+5n-3n^2}{4n+3n^2}+\frac{32+n-3n^2}{8n+3n^2}+\frac{48-3n-3n^2}{12n+3n^2}+\dots +\frac{25n-7n^2}{7n^2}$. Then, the value of $\underset{n\to \infty }{\lim }f\left(n\right)$ is equal to

The straight line \(2 x-3 y=1\) divides the circular region \(x^2+y^2 \leq 6\) into two parts. If \(S=\left\{\left(2, \frac{3}{4}\right),\left(\frac{5}{2}, \frac{3}{4}\right),\left(\frac{1}{4},-\frac{1}{4}\right),\left(\frac{1}{8}, \frac{1}{4}\right)\right\}\), then the number of point(s) in \(S\) lying inside the smaller part is

Three numbers are chosen at random, one after another with replacement, from the set \(S=\{1,2,3, \ldots, 100\}\). Let \(p_{1}\) be the probability that the maximum of chosen numbers is at least 81 and \(p_{2}\) be the probability that the minimum of chosen numbers is at most 40 .
The value of $\frac{625}{4}{p}_1$ is

Let $f\left(x\right)=x+{\log }_{e}x-x{\log }_{\mathrm{e}}x,x\in \left(0, \infty \right)$
$•$   Column 1 contains information about zeros of $f\left(x\right)$ , $f\text{'}\left(x\right)$ and $f\text{'}\text{'}\left(x\right)$
$•$   Column 2 contains information about the limiting behaviour of $f\left(x\right)$ , $f\text{'}\left(x\right)$ and $f\text{'}\text{'}\left(x\right)$ at infinity.
$•$   Column 3 contains information about increasing-decreasing nature of $f\left(x\right)$ and $f\text{'}\left(x\right)$

Column 1	Column 2	Column 3
(I) $f\left(x\right)=0$ for some $x\in \left(1, e^2\right)$	(i) $\underset{x\to \infty }{\lim }f\left(x\right)=0$	(P) $f$ is increasing in $(0, 1)$
(II) $f^{\prime }\left(x\right)=0$ for some $x in \left(1, e\right)$	(ii) $\underset{x\to \infty }{\lim }f\left(x\right)=-\infty$	(Q) $f$ is decreasing in $\left(e, e^2\right)$
(III) $f^{\prime }\left(x\right)=0$ for some $x\in \left(0, 1\right)$	(iii) $\underset{x\to \infty }{\lim }{f}^{\prime }\left(x\right)=-\infty$	(R) $f^{\prime }$ is increasing in $(0, 1)$
(IV) $f^{\prime \prime }\left(x\right)=0$ for some $x\in \left(1, e\right)$	(iv) $\underset{x\to \infty }{\lim }{f}^{\prime \prime }\left(x\right)=0$	(S) $f^{\prime }$ is decreasing in $\left(e, e^2\right)$

A factory has a total of three manufacturing units, \(M_1, M_2\), and \(M_3\), which produce bulbs independent of each other. The units \(M_1, M_2\), and \(M_3\) produce bulbs in the proportions of 2:2:1, respectively. It is known that \(20 \%\) of the bulbs produced in the factory are defective. It is also known that, of all the bulbs produced by \(M_1, 15 \%\) are defective. Suppose that, if a randomly chosen bulb produced in the factory is found to be defective, the probability that it was produced by \(M_2\) is \(\frac{2}{5}\).
If a bulb is chosen randomly from the bulbs produced by \(M_3\), then the probability that it is defective is ____.

Suppose $\det \left[\begin{array}{cc}\sum _{k=0}^{n}k& \sum _{k=0}^n{}_{\mathrm{ }}{}^n{C}_k{k}^2\\ \sum _{k=0}^n{}_{\mathrm{ }}{}^n{C}_{k}k& \sum _{k=0}^n{}_{\mathrm{ }}{}^n{C}_k{3}^k\end{array}\right]=0,$ holds for some positive integer $n.$ Then $\sum _{k=0}^n\frac{{}_{ }{}^n{C}_k}{k+1}$ equals

The circle $C_1:x^2+y^2=3,$ with centre at O, intersects the parabola $x^2=2y$ at the point P in the first quadrant. Let the tangent to the circle $C_1$ at P touches other two circles $C_2$ and $C_3$ at $R_2$ and $R_3$ , respectively. Suppose $C_2$ and $C_3$ have equal radii $2\sqrt{3}$ and centres $Q_2$ and ${ Q}_3$ , respectively. If $Q_2$ and $Q_3$ lie on the y - axis, then

A thin uniform annular disc (see figure) of mass \(M\) has outer radius \(4 R\) and inner radius \(3 R\). The work required to take a unit mass from point \(P\) on its axis to infinity is

The increasing order of atomic radii of the following group $13$ elements is

Consider the system of equations \(x-2 y+3 z=-1, x-3 y+4 z=1\) and \(-x+y-2 z=k\)
Statement 1 The system of equations has no solution for \(k \neq 3\).
Statement 2 The determinant \(\left|\begin{array}{ccc}1 & 3 & -1 \\ -1 & -2 & k \\ 1 & 4 & 1\end{array}\right| \neq 0\), for \(k \neq 3\).

Monocyclic compounds \(\mathbf{P}, \mathbf{Q}, \mathbf{R}\) and \(\mathbf{S}\) are the major products formed in the reaction sequences given below.


The product having the highest number of unsaturated carbon atom(s) is-

Three moles of ${\mathrm{B}}_2{\mathrm{H}}_6$ are completely reacted with methanol. The number of moles of boron containing product formed is

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Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately \(6.023 \times 10^{23}\) ) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.
A \(4.0\) molar aqueous solution of \(\mathrm{NaCl}\) is prepared and \(500 \mathrm{~mL}\) of this solution is electrolysed. This leads to the evolution of chlorine gas at one of electrodes (atomic mass: \(\mathrm{Na}=23, \mathrm{Hg}=200 ; 1\) faraday \(=96500\) coulombs).
Question:
The total charge (coulombs) required for complete electrolysis is