Monocyclic compounds \(\mathbf{P}, \mathbf{Q}, \mathbf{R}\) and \(\mathbf{S}\) are the major products formed in the reaction sequences given below.


The product having the highest number of unsaturated carbon atom(s) is-

Total number of cis $\mathrm{N}-\mathrm{M}\mathrm{n}-\mathrm{C}\mathrm{l}$ bond angles (that is, $\mathrm{M}\mathrm{n}-\mathrm{N}$ and $\mathrm{M}\mathrm{n}-\mathrm{C}\mathrm{l}$ bonds in cis positions) present in a molecule of cis- $\left[\mathrm{M}\mathrm{n}{\left(\mathrm{e}\mathrm{n}\right)}_2{\mathrm{C}\mathrm{l}}_2\right]$ complex is _________ $\left(en={\mathrm{N}\mathrm{H}}_2{\mathrm{C}\mathrm{H}}_2{\mathrm{C}\mathrm{H}}_2{\mathrm{N}\mathrm{H}}_2\right)$

For one mole of a van der Waal's gas when \(b=0\) and \(\mathrm{T}=300 \mathrm{~K}\), the PV vs, \(1 / \mathrm{V}\) plot is shown below. The value of the van der Waal's constant \(a\) (atm. liter \({ }^{2} \mathrm{~mol}^{-2}\) ) is :

The compound (s) that exhibit (s) geometrical isomerism is (are)

The IUPAC name of \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{COCl}\) is

Among the following, intensive property is (properties are)

A list of species having the formula XZ4 is given below.
\(\text{XeF} _4, \text{SF} _4, \text{SiF} _4, \text{BF} _4^{-}, \text{BrF} _4^{-},\left[\text{Cu} \left(\text{NH} _3\right)_4\right]^{2+},\) \(\left[\text{FeCl} _4\right]^{2-},\left[\text{CoCl} _4\right]^{2-}\) and \(\left[\text{PtCl} _4\right]^{2-}\)
Defining shape on the basis of the location of X and Z atoms, the total number of species having a square planar shape is

Let $a, b, c$ be three non-zero real numbers such that the equation $\sqrt{3}a\cos x+2b\sin x=c, x\in \left[-\frac{\pi }{2}, \frac{\pi }{2}\right]$ has two distinct real roots $\alpha$ and $\beta$ with $\alpha +\beta =\frac{\pi }{3}$. Then, the value of $\frac{b}{a}$ is

In thermodynamics, the $\mathrm{P}-\mathrm{V}$ work done is given by $\mathrm{w}=-\int {\mathrm{dVP}}_{\mathrm{ext}}$. For a system undergoing a particular process, the work done is,
$\mathrm{w}=-\int \mathrm{dV}\left(\frac{\mathrm{RT}}{\mathrm{V}-\mathrm{b}}-\frac{\mathrm{a}}{{\mathrm{V}}^2}\right)$. This equation is applicable to a

Considering only the principal values of the inverse trigonometric functions, the value of \(\tan \left(\sin ^{-1}\left(\frac{3}{5}\right)-2 \cos ^{-1}\left(\frac{2}{\sqrt{5}}\right)\right)\) is

The number of values of \(\theta\) in the interval \(\left(-\frac{\pi}{2}, \frac{\pi}{2}\right)\) such that \(\theta \neq \frac{n \pi}{5}\) for \(n=0, \pm 1, \pm 2\) and \(\tan \theta=\cot 5 \theta\) as well as \(\sin 2 \theta=\cos 4 \theta\) is

Paragraph : If the measurement errors in all the independent quantities are known, then it is possible to determine the error in any dependent quantity. This is done by the use of series expansion and truncating the expansion at the first power of the error. For example, consider the relation $z =\frac{x}{y}$. If the errors in $x, y \mathrm{a}\mathrm{n}\mathrm{d} z \mathrm{a}\mathrm{r}\mathrm{e} ∆x, ∆y \mathrm{a}\mathrm{n}\mathrm{d} ∆z$ , respectively, then

$z\pm ∆z=\frac{x\pm ∆x}{y\pm ∆y}=\frac{x}{y}\left(1\pm \frac{∆x}{x}\right){\left(1\pm \frac{∆y}{y}\right)}^{-1}$

The series expansion for ${\left(1\pm \frac{∆y}{y}\right)}^{-1}$, to first power in $∆y/y, \mathrm{i}\mathrm{s} 1\mp \left(∆y/y\right)$. The relative errors in independent variables are always added. So the error in $z$ will be

$\text{Δ}z=z\left(\frac{\text{Δ}x}{x}+\frac{\text{Δ}y}{y}\right).$
The above derivation makes the assumption that \(\Delta r / x \ll 1, \Delta y / y < 1\). Therefore, the higher powers of these quantities are neglected.
Question : Consider the ratio \(r=\frac{(1-a)}{(1+a)}\) to be determined by measuring a dimensionless quantity a If the error in the measurement of a is \(\Delta a(\frac{\Delta a}{a}<<1)\), then what is the error \(\Delta r\) in determining \(r\) ?

The figures below depict two situations in which two infinitely long static line charges of constant positive line charge density $\mathrm{\lambda }$ are kept parallel to each other. In their resulting electric field, point charges $\mathrm{q}$ and $-\mathrm{q}$ are kept in equilibrium between them. The point charges are confined to move in the $\mathrm{x}$ direction only. If they are given a small displacement about their equilibrium positions, then the correct statements(s) is (are)