ExamBro
ExamBro
JEE Advanced · Chemistry · 6. Thermodynamics (C)

The standard enthalpies of formation of CO2(g) , H 2 O l and glucose (s) at 2 5 o C are  - 400 kJ / mol , - 300 kJ / mol and - 1300 kJ / mol , respectively. The standard enthalpy combustion per gram of glucose at 2 5 o C is  ( Δ H f 0 =1300kJmo l forglucose )

  1. A + 2900 kJ
  2. B - 2900 kJ
  3. C - 16.11 kJ
  4. D + 16.11 kJ
Verified Solution

Answer & Solution

Correct Answer

(C) - 16.11 kJ

Step-by-step Solution

Detailed explanation

Heat of combustion : It is the amount of heat evolved or absorbed (i.e. change in enthalpy) when one mole of the substance is completely burnt in air or oxygen.
Standard enthalpy of combustion of glucose reaction is given as
\(C _6 H _{12} O _{6(s)}+6 O _{2(g)} \rightarrow 6 CO _{2(g)}+6 H _2 O (l)\)
\(\Delta H _{ C }^{ o }=\Sigma_{\text {Product }} \Delta H _{ f }^{ o }-\Sigma_{\text {Reactant }} \Delta H _{ f }^{ o }\)
\(=\{6(-400)+6(-300)\}_{\text {Product }}-\{-1300\) \(\times ~1+6 \times 0\}_{\text {Reactant }}\)
\(=-2400-1800+1300=-2900 kJ mole ^{-1}\)
Molecular mass of glucose \(=72+12+96=180 g /\) mole
\(\Delta H _{ C }^{ o } /\) gram of glucose \(=\frac{-2900}{180}=-16.11 kJ / g\).
Same subject
Explore more questions on app
From JEE Advanced
Explore more questions on app