For the first order reaction \(2 \mathrm{~N}_2 \mathrm{O}_5(\mathrm{~g}) \longrightarrow 4 \mathrm{NO}_2(g)+\mathrm{O}_2(g)\)

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The vapour pressure of the solution \(M\) is

Among the following compounds, the most acidic is

A monoatomic ideal gas undergoes a process in which the ratio of \(P\) to \(V\) at any instant is constant and equals to 1 . What is the molar heat capacity of the gas?

The dissociation constant of a substituted benzoic acid at \(25^{\circ} \mathrm{C}\) is \(1.0 \times 10^{-4}\). The \(\mathrm{pH}\) of \(0.01 \mathrm{M}\) solution of its sodium salt is

A trinitro compound, $1,3,5$-tris-($4$-nitrophenyl) benzene, on complete reaction with an excess of $\mathrm{Sn}/\mathrm{HCl}$ gives a major product, which on treatment with an excess of ${\mathrm{NaNO}}_2/\mathrm{HCl}$ at $0°\mathrm{C}$ provides $\mathbf{P}$ as the product. $\mathbf{P}$, upon treatment with excess of ${\mathrm{H}}_2\mathrm{O}$ at room temperature, gives the product $\mathbf{Q}$. Bromination of $\mathbf{Q}$ in aqueous medium furnishes the product $\mathbf{R}$. The compound $\mathbf{P}$ upon treatment with an excess of phenol under basic conditions gives the product $\mathbf{S}$. The molar mass difference between compounds $\mathbf{Q}$ and $\mathbf{R}$ is $474 \mathrm{g} {\mathrm{mol}}^{-1}$ and between compounds $\mathbf{P}$ and $\mathbf{S}$ is $172.5 \mathrm{g} {\mathrm{mol}}^{-1}$.
The number of heteroatoms present in one molecule of \(R\) is [Use: Molar mass (in \(\text{g mol} -1\) ): \(H =1,\) \(C =12, N=14, O =16,\) \(Br =80, Cl =35.5\) Atoms other than C and H are considered as heteroatoms]

The pair(s) of diamagnetic ions is(are)

A cubical solid aluminum (bulk modulus \(=-\text V \frac{\text{dP}}{\text{dV}}=70\text{ GPa}\)) block has an edge length of 1 m on the surface of the earth. It is kept on the floor of a 5 km deep ocean. Taking the average density of water and the acceleration due to gravity to be \(10^3\text{ kg m} ^{-3}\) and \(10\text{ ms} ^{-2}\), respectively, the change in the edge length of the block in mm is _____________ .

The Henry's law constant for the solubility of \(\mathrm{N}_2\) gas in water at \(298 \mathrm{~K}\) is \(1.0 \times 105 \mathrm{~atm}\). The mole fraction of \(\mathrm{N}_2\) in air is \(0.8\). The number of moles of \(\mathrm{N}_2\) from air dissolved in 10 moles of water of \(298 \mathrm{~K}\) and \(5 \mathrm{~atm}\) pressure is

An annular disk of mass $M$, inner radius $a$ and outer radius $b$ is placed on a horizontal surface with coefficient of friction $\mu$, as shown in the figure. At some time, an impulse $J_0\stackrel{\wedge }{x}$ is applied at a height $h$ above the center of the disk. If $h=h_m$ then the disk rolls without slipping along the $x$-axis. Which of the following statement(s) is(are) correct?

In a high school, a committee has to be formed from a group of $6$ boys
$M_1, M_2, M_3, M_4, M_5, M_6$ and $5$ girls $G_1, G_2, G_3, G_4, G_5$.
(i) Let ${\alpha }_1$ be the total number of ways in which the committee can be formed such that the committee has $5$ members, having exactly $3$ boys and $2$ girls.
(ii) Let ${\alpha }_2$ be the total number of ways in which the committee can be formed such that the committee has at least $2$ members, and having an equal number of boys and girls.
(iii) Let ${\alpha }_3$ be the total number of ways in which the committee can be formed such that the committee has $5$ members, at least $2$ of them being girls.
(iv) Let ${\alpha }_4$ be the total number of ways in which the committee can be formed such that the committee has $4$ members, having at least $2$ girls and such that both $M_1$ and $G_1$ are NOT in the committee together.

LIST-I	LIST-II
A. The value of ${\alpha }_1$ is	P. $136$
B. The value of ${\alpha }_2$ is	Q. $189$
C. The value of ${\alpha }_3$ is	R. $192$
D. The value of ${\alpha }_4$ is	S. $200$
	T. $381$
	U. $461$

The correct option is:

Let $\widehat{u}=u_1\widehat{i}+u_2\widehat{j}+u_3\widehat{k}$ be a unit vector in ${\mathbb{R}}^3$ and $\widehat{w}=\frac{1}{\sqrt{6}} \left(\widehat{i}+ \widehat{j}+2\widehat{k}\right).$ Given that there exists a vector $\overrightarrow{v}$ in ${\mathbb{R}}^3$ such that $\left|\widehat{u}\times \overrightarrow{v}\right|=1$ and $\widehat{w} . \left(\widehat{u}\times \overrightarrow{v}\right)=1.$ Which of the following statement(s) is (are) correct ?

Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code given below the lists
\(\left\{\right.\)en \(= H _2 NCH _2 CH _2 NH _2 ;\) atomic numbers \(\left.: T _{ i }=22, Cr =24 ; Co =27 ; Pt =78\right\}\)

	List – I		List – II
A.	$\left[\mathrm{C}\mathrm{r}{\left(\mathrm{N}{\mathrm{H}}_3\right)}_4\mathrm{C}{\mathrm{l}}_2\right]\mathrm{C}\mathrm{l}$	P.	Paramagnetic and exhibits ionization isomerism
B.	$\left[\mathrm{T}\mathrm{i}{\left({\mathrm{H}}_2\mathrm{O}\right)}_5\mathrm{ }\mathrm{C}\mathrm{l}\right]{\left(\mathrm{N}{\mathrm{O}}_3\right)}_2$	Q.	Diamagnetic and exhibits cis - trans isomerism
C.	$\left[\mathrm{P}\mathrm{t}\left(\mathrm{e}\mathrm{n}\right)\left(\mathrm{N}{\mathrm{H}}_3\right)\mathrm{C}\mathrm{l}\right]\mathrm{N}{\mathrm{O}}_3$	R.	Paramagnetic and exhibits cis - trans isomerism
D.	$\left[\mathrm{C}\mathrm{o}{\left(\mathrm{N}{\mathrm{H}}_3\right)}_4{\left(\mathrm{N}{\mathrm{O}}_3\right)}_2\right]\mathrm{N}{\mathrm{O}}_3$	S.	Diamagnetic and exhibits ionization isomerism