Paragraph:
An acylic hydrocarbon \(P\), having molecular formula \(\mathrm{C}_6 \mathrm{H}_{10}\), gave acetone as the only organic product through the following sequence of reactions, in which \(Q\) is an intermediate organic compounds.

Question:
The structure of compound P is

The entropy versus temperature plot for phases $\alpha$ and $\beta$ at $1$ bar pressure is given. ${\mathrm{S}}_{\mathrm{T}}$ and ${\mathrm{S}}_0$ are entropies of the phases at temperatures $\mathrm{T}$ and $0 \mathrm{K}$, respectively. The transition temperature for $\alpha$ to $\beta$ phase change is $600 \mathrm{K}$ and ${\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}-{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}=1 \mathrm{J} {\mathrm{mol}}^{-1} {\mathrm{K}}^{-1}$. Assume $\left({\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}-{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}\right)$ is independent of temperature in the range of $200$ to $700 \mathrm{K}.{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}$ and ${\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}$ are heat capacities of $\alpha$ and $\beta$ phases, respectively. The value of enthalpy change, ${\mathrm{H}}_{\beta }-{\mathrm{H}}_{\alpha }$ (in ${\mathrm{Jmol}}^{-1}$ ), at $300 \mathrm{K}$ is

The nitrogen containing compound produced in the reaction of $\mathrm{H}\mathrm{N}{\mathrm{O}}_3$ with ${\mathrm{P}}_4{\mathrm{O}}_{10}$

Molar volume \(\left(V_m\right)\) of a van der Waals gas can be calculated by expressing the van der Waals equation as a cubic equation with \(V_m\) as the variable. The ratio (in \(\mathrm{mol} \mathrm{dm}^{-3}\) ) of the coefficient of \(V_m^2\) to the coefficient of \(V_m\) for a gas having van der Waals constants \(a=6.0 \mathrm{dm}^6 \mathrm{~atm} \mathrm{~mol}^{-2}\) and \(b=0.060 \mathrm{dm}^3 \mathrm{~mol}^{-1}\) at 300 K and 300 atm is _____ .
Use: Universal gas constant \((R)=0.082 \mathrm{dm}^3 \mathrm{~atm} \mathrm{~mol}{ }^{-1} \mathrm{~K}^{-1}\)

Native silver metal forms a water soluble complex with a dilute aqueous solution of \(\mathrm{NaCN}\) in the presence of

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Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite \(\left(\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}\right)\), atacamite \(\left(\mathrm{Cu}_2 \mathrm{Cl}(\mathrm{OH})_3\right)\), cuprite \(\left(\mathrm{Cu}_2 \mathrm{O}\right)\), copper glance \(\left(\mathrm{Cu}_2 \mathrm{~S}\right)\) and malachite \(\left(\mathrm{Cu}_2(\mathrm{OH})_2 \mathrm{CO}_3\right)\). However, 80\% of the world copper production comes from the ore chalcopyrite \(\left(\mathrm{CuFeS}_2\right)\). The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.
Question:
In self-reduction, the reducing species is

Paragraph I: An organic compound \(\mathbf{P}\) with molecular formula \(\mathrm{C}_9 \mathrm{H}_{18} \mathrm{O}_2\) decolorizes bromine water and also shows positive iodoform test. \(\mathbf{P}\) on ozonolysis followed by treatment with \(\mathrm{H}_2 \mathrm{O}_2\) gives \(\mathbf{Q}\) and \(\mathbf{R}\). While compound \(\mathbf{Q}\) shows positive iodoform test, compound \(\mathbf{R}\) does not give positive iodoform test. \(\mathbf{Q}\) and \(\mathbf{R}\) on oxidation with pyridinium chlorochromate (PCC) followed by heating give \(\mathbf{S}\) and \(\mathbf{T}\), respectively. Both \(\mathbf{S}\) and \(\mathbf{T}\) show positive iodoform test.
Complete copolymerization of 500 moles of \(\mathbf{Q}\) and 500 moles of \(\mathbf{R}\) gives one mole of a single acyclic copolymer \(\mathbf{U}\).
[Given, atomic mass: \(\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16\)]
Question: Sum of number of oxygen atoms in \(\mathbf{S}\) and \(\mathbf{T}\) is

A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in equilibrium at temperature $\mathrm{T}$ . Assuming the gases are ideal, the correct statement(s) is (are)

For \(0 < \theta < \frac{\pi}{2}\), the solution(s) of \(\sum_{m=1}^6 \operatorname{cosec}\left[\theta+\frac{(m-1) \pi}{4}\right]\) \(\operatorname{cosec}\left(\theta+\frac{m \pi}{4}\right)=4 \sqrt{2}\) is/are

A particle of mass $m$ moves in circular orbits with potential energy $U\left(r\right)=Fr$, where $F$ is a positive constant and $r$ is its distance from the origin. Its energies are calculated using the Bohr model. If the radius of the particle's orbit is denoted by $R$ and its speed and energy are denoted by $v$ and $E$ respectively, then for the $n^{\mathrm{th}}$ orbit (here $h$ is the Planck's constant)

When \(20 \mathrm{~g}\) of naphthoic acid \(\left(\mathrm{C}_{11} \mathrm{H}_8 \mathrm{O}_2\right)\) is dissolved in \(50 \mathrm{~g}\) of benzene \(\left(K_f=1.72 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)\), a freezing point depression of \(2 \mathrm{~K}\) is observed. The van't Hoff factor \((i)\) is

One mole of a monoatomic ideal gas goes through a thermodynamic cycle, as shown in the volume versus temperature $\left(\mathrm{V}-\mathrm{T}\right)$ diagram. The correct statement(s) is/are:
[ $\mathrm{R}$ is the gas constant]

In the given circuit, a charge of \(+80 \mu C\) is given to the upper plate of the \(4 \mu F\) capacitor. Then in the steady state, the charge on the upper plate of the \(3 \mu F\) capacitor is