The correct statement $\left(\mathrm{s}\right)$ related to the metal extraction processes is(are)

The correct order of the wavelength maxima of the absorption band in the ultraviolet-visible region for the given complexes is

The total number of contributing structures showing hyperconjugation (involving \(\mathrm{C}-\mathrm{H}\) bonds) for the following carbocation is

Statement \(\mathbf{1}\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{NO}\right] \mathrm{SO}_4\) is paramagnetic.
Statement 2 The \(\mathrm{Fe}\) in \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{NO}\right] \mathrm{SO}_4\) has three unpaired electrons.

We have taken a saturated solution of \(\mathrm{AgBr}, K_{\mathrm{sp}}\) is \(12 \times 10^{-14}\). If \(10^{-7}\) mole of \(\mathrm{AgNO}_3\) are added to 1 litre of this solution, find conductivity (specific conductance) of this solution in terms of \(10^{-7} \mathrm{Sm}^{-1}\) units.
\( \text {Given, } \lambda_{\left(\mathrm{Ag}^{+}\right)}^{\circ} =6 \times 10^{-3} \mathrm{Sm}^2 \mathrm{~mol}^{-1},\) \(\lambda_{\left(\mathrm{Br}^{-}\right)}^{\circ}=8 \times 10^{-3} \mathrm{Sm}^2 \mathrm{~mol}^{-1}, \)
\( \lambda_{\left(\mathrm{NO}_3^{-}\right)} =7 \times 10^{-3} \mathrm{Sm}^2 \mathrm{~mol}^{-1},\)

Paragraph:

The amount of energy required to break a bond is same as the amount of energy released when the same bond is formed. In gaseous state, the energy required for homolytic cleavage of a bond is called Bond Dissociation Energy (BDE) or Bond Strength. BDE is affected by \(s\)-character of the bond and the stability of the radicals formed. Shorter bonds are typically stronger bonds. BDEs for some bonds are given below:












Question:
Correct match of the \(\mathbf{C}-\mathbf{H}\) bonds (shown in bold) in Column \(\mathbf{J}\) with their BDE in Column \(\mathbf{K}\) is

Paragraph:
An aqueous solution of a mixture of two inorganic salts, when treated with dilute \(H C\) ?, gave a precipitate \((\boldsymbol{P})\) and a filtrate \((\boldsymbol{Q})\). The precipitate \(\boldsymbol{P}\) was found to dissolve in hot water. The filtrate \((\boldsymbol{Q})\) remained unchanged, when treated with \(\mathrm{H}_{2} \mathrm{~S}\) in a dilute mineral acid medium. However, it gave a precipitate \((\boldsymbol{R})\) with \(H_{2} S\) in an ammoniacal medium. The precipitate \(\boldsymbol{R}\) gave a coloured solution \((\boldsymbol{S})\), when treated with \(\mathrm{H}_{2} \mathrm{O}_{2}\) in an aqueous \(\mathrm{NaOH}\) medium.
Question:
The coloured solution \(\boldsymbol{S}\) contains

Let $A=\left\{\frac{1967+1686i \sin \theta }{7-3i \cos \theta }: \theta \in R\right\}$. If $A$ contains exactly one positive integer $n$, then the value of $n$ is

A parallel plate capacitor \(C\) with plates of unit area and separation \(d\) is filled with a liquid of dielectric constant \(K=2\). The level of liquid is \(\frac{d}{3}\) initially. Suppose the liquid level decreases at a constant speed \(v\), the time constant as a function of time \(t\) is

Let \(f(x)=x^2\) and \(g(x)=\sin x\) for all \(x \in R\). Then, the set of all \(x\) satisfying \((\) fogogof \()(x)=(\operatorname{gogof})(x)\), where \((f \circ g)(x)=f(g(x))\) is

Paragraph:
The noble gases have closed-shell electronic configuration and are monoatomic gases under normal conditions. The low boiling points of the lighter noble gases are due to weak dispersion forces between the atoms and the absence of other interatomic interactions.
The direct reaction of xenon with fluorine leads to a series of compounds with oxidation numbers \(+2,+4\) and \(+6 . \mathrm{XeF}_4\) reacts violently with water to give \(\mathrm{XeO}_3\). The compounds of xenon exhibit rich stereochemistry and their geometries can be deduced considering the total number of electron pairs in the valence shell.
Question:
Argon is used in are welding because of its

Match List I with List II and select the correct answer using the codes given below the lists:

	\(\text{List I}\)		\(\text{List II}\)
a.	Boltzmann constant	p.	\(\left[M L^2 T^{-1}\right]\)
b.	Coefficient of viscosity	q.	\(\left[M L^{-1} T^{-1}\right]\)
c.	Planck constant	r.	\(\left[M L T^{-3} K^{-1}\right]\)
d.	Thermal conductivity	s.	\(\left[M L^2 T^{-2} K^{-1}\right]\)

Paragraph: Let $S$ be the circle in the $xy$ – plane defined by the equation $x^2 + y^2 = 4.$

Question : Let $P$ be a point on the circle $S$ with both coordinates being positive. Let the tangent to $S$ at $P$ intersect the coordinate axes at the points $M$ and $MN$ Then, the mid-point of the line segment must lie on the curve