The correct combination of names for isomeric alcohols with molecular formula ${\mathrm{C}}_4{\mathrm{H}}_{10}\mathrm{O}$ is/are

The correct order of acidity for the following compounds is :

The correct order of acid strength of the following carboxylic acids is -

List-I contains various reaction sequences and List-II contains the possible products. Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

Which is correct statement if \(\mathrm{N}_2\) is added at equilibrium condition?

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Tollen's reagent is used for the detection of aldehyde when a solution of \(\mathrm{AgNO}_3\) is added to glucose with \(\mathrm{NH}_4 \mathrm{OH}\) then gluconic acid is formed
\(\mathrm{Ag}^{+}+e^{-} \rightarrow \mathrm{Ag} E_{\text {red }}^{\circ}=0.8 \mathrm{~V} \)
\( \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{H}_2 \mathrm{O} \rightarrow \text { Gluconic acid }\)\(\left(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_7\right)+2 \mathrm{H}^{+}+2 e^{-} ; -E_{\mathrm{red}}^{\circ}=\) \(-0.05 \mathrm{~V} \)
\( \mathrm{Ag}\left(\mathrm{NH}_3\right)_2^{+}+e^{-} \rightarrow \mathrm{Ag}(s)+2 \mathrm{NH}_3 ;\) \(E_{\mathrm{red}}^{\circ}=0.337 \mathrm{~V}\)
[Use \(2.303 \times \frac{R T}{F}=0.0592\) and \(\frac{F}{R T}=38.92\) at \(298 \mathrm{~K}\) ]
Question:
Ammonia is always added in this reaction. Which of the following must be incorrect?

The substituents \(R_{1}\) and \(R_{2}\) for nine peptides are listed in the table given below. How many of these peptides are positively charged at \(\mathrm{pH}=7.0\) ?

\(\begin{array}{|c|c|c|}\hline Peptide & \mathbf{R}_{\mathbf{1}} & \mathbf{R}_{\mathbf{2}} \\\hline I & \mathrm{H} & \mathrm{H} \\\hline II & \mathrm{H} & \mathrm{CH}_{3} \\\hline III & \mathrm{CH}_{2} \mathrm{COOH} & \mathrm{H} \\\hline IV & \mathrm{CH}_{2} \mathrm{CONH}_{2} & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} \\\hline V & \mathrm{CH}_{2} \mathrm{CONH}_{2} & \mathrm{CH}_{2} \mathrm{CONH}_{2} \\\hline VI & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} \\\hline VII & \mathrm{CH}_{2} \mathrm{COOH} & \mathrm{CH}_{2} \mathrm{CONH}_{2} \\\hline VIII & \mathrm{CH}_{2} \mathrm{OH} & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} \\\hline IX & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} & \mathrm{CH}_{3} \\\hline\end{array}\)

A positron is emitted from \({ }_{11}^{23} \mathrm{Na}\). The ratio of the atomic mass and atomic number of the resulting nuclide is

For a real number $\alpha ,$ if the system $\left[\begin{array}{ccc}1& \alpha & {\alpha }^2\\ \alpha & 1& \alpha \\ {\alpha }^2& \alpha & 1\end{array}\right] \left[\begin{array}{c}x\\ y\\ z\end{array}\right]=\left[\begin{array}{c}1\\ -1\\ 1\end{array}\right]$ of linear equations, has infinitely many solutions, then $1+\alpha +{\alpha }^2=$

Using the data provided, calculate the multiple bond energy \(\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)\) of a \(\mathrm{C} \equiv \mathrm{C}\) bond in \(\mathrm{C}_{2} \mathrm{H}_{2}\). That energy is (take the bond energy of a \(\mathrm{C}-\mathrm{H}\) bond as \(350 \mathrm{~kJ} \mathrm{~mol}^{-1}\) ) \(2 \mathrm{C}(\mathrm{s})+\mathrm{H}_{2}(\mathrm{~g}) \longrightarrow \mathrm{HC}=\mathrm{CH}(\mathrm{g}) ; \Delta \mathrm{H}=\) \(225 \mathrm{~kJ} \mathrm{~mol}^{-1}\) \(2 \mathrm{C}(\mathrm{s}) \longrightarrow 2 \mathrm{C}(\mathrm{g}) ; \Delta \mathrm{H}=1410 \mathrm{~kJ} \mathrm{~mol}^{-1}\) \(\mathrm{H}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{H}(\mathrm{g}) ; \Delta \mathrm{H}=330 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

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The key feature of Bohr's theory of spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid. The rule to be applied is Bohr's quantization condition.
Question:
It is found that the excitation frequency from ground to the first excited state of rotation for the \(\mathrm{CO}\) molecule is close to \(\frac{4}{\pi} \times 10^{11} \mathrm{~Hz}\). Then the moment of inertia of CO molecule about its centre of mass is close to (Take \(h=2 \pi \times 10^{-34} J-s\) )

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The nuclear charge \((\mathrm{Ze})\) is non-uniformly distributed within a nucleus of radius \(R\). The charge density \(\rho(r)\) [charge per unit volume] is dependent only on the radial distance \(r\) from the centre of the nucleus as shown in figure. The electric field is only along the radial direction.

Question:
The electric field within the nucleus is generally observed to be linearly dependent on \(r\). This implies

A solid horizontal surface is covered with a thin layer of oil. A rectangular block of mass $m=0.4kg$ is at rest on this surface. An impulse of $1.0 N s$ is applied to the block at time $t=0$ so that it starts moving along the x-axis with a velocity $v\left(t\right)=v_0{e}^{-\frac{t}{\tau }}$ , where $v_0$ is a constant and $\tau =4$ . The displacement of the block, in meter, at $t=\tau$ is __________. Take $e^{-1}=0.37$