The correct acidity order of the following is

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The vapour pressure of the solution \(M\) is

In the Newman projection for 2,2-dimethylbutane

\(X\) and \(Y\) can respectively be

The electrochemical cell shown below is a concentration cell. \(\mathrm{M} \mid \mathrm{M}^{2+}\) (saturated solution of a sparingly soluble salt, \(\left.\mathrm{MX}_{2}\right) \| \mathrm{M}^{2 \perp}\left(0.001 \mathrm{~mol} \mathrm{dm}^{-3}\right) \mid \mathrm{M}\).
The emf of the cell depends on the difference in concentrations of \(\mathrm{M}^{2+}\) ions at the two electrodes. The emf of the cell at \(298 \mathrm{~K}\) is \(0.059 \mathrm{~V}\).
Question:
The value of \(\Delta \mathrm{G}\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)\) for the given cell is (take 1 \(\mathrm{F}=96500 \mathrm{Cmol}^{-1}\) )

The total number of compounds having at least one bridging oxo group among the molecules given below is
\(\text N _2\text O _5,\)\(\text P _4\text O _6,\)\(\text P _4\text O _8,\)\(\text H _4\text P _2\text O _5,\)\(\text H _5\text P _3\text O _{10},\) \(\text H _2\text S_2\text O _3,\text H _2\text S_2\text O _5\)

Total number of hydroxyl groups present in a molecule of the major product $\mathrm{P}$ is ______

Among the following metal carbonyls, the \(\mathrm{C}-\mathrm{O}\) bond order is lowest in

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A frame of reference that is accelerated with respect to an inertial frame of reference is called a non-inertial frame of reference. A coordinate system fixed on a circular disc rotating about a fixed axis with a constant angular velocity \(\omega\) is an example of a non-inertial frame of reference.

The relationship between the force \(\vec{F}_{\text {rot }}\) experienced by a particle of mass \(m\) moving on the rotating disc and the force \(\vec{F}_{\text {in }}\) experienced by the particle in an inertial frame of reference is

\(\vec{F}_{\mathrm{rot}}=\vec{F}_{\mathrm{in}}+2 m\left(\vec{v}_{\mathrm{rot}} \times \vec{\omega}\right)+m(\vec{\omega} \times \vec{r}) \times \vec{\omega}\),

where \(\vec{v}_{\text {rot }}\) is the velocity of the particle in the rotating frame of reference and \(\vec{r}\) is the position vector of the particle with respect to the centre of the disc.

Now consider a smooth slot along a diameter of a disc of radius \(R\) rotating counter-clockwise with a constant angular speed \(\omega\) about its vertical axis through its center. We assign a coordinate system with the origin at the center of the disc, the \(x\)-axis along the slot, the \(y\)-axis perpendicular to the slot and the \(z\)-axis along the rotation axis \((\vec{\omega}=\omega \hat{k}) .\) A small block of mass \(m\) is gently placed in the slot at \(\vec{r}=(R / 2) \hat{i}\) at \(t=0\) and is constrained to move only along the slot.

Question :
The net reaction of the disc on the block is

For every integer \(n\), let \(a_{n}\) and \(b_{n}\) be real numbers. Let function \(f: I R \rightarrow I R\) be given by

\(f(x)=\left\{\begin{array}{lll}

a_{n}+\sin \pi x, & \text { for } & x \in[2 n, 2 n+1] \\

b_{n}+\cos \pi x, & \text { for } & x \in(2 n-1,2 n)

\end{array}\right.\)

for all integers \(n\). If \(f\) is continuous, then which of the following hold \((s)\) for all \(n\) ?

Statement \(1 \mathrm{~Pb}^{4+}\) compounds are stronger oxidising agents than \(\mathrm{Sn}^{4+}\) compounds.
Statement 2 The higher oxidation states for the group 14 elements are more stable for the heavier members of the group due to 'inert pair effect'.

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Tangents are drawn from the point \(P(3,4)\) to the ellipse \(\frac{x^2}{9}+\frac{y^2}{4}=1\) touching the ellipse at points \(A\) and \(B\).Question:
The equation of the locus of the point whose distance from the point \(P\) and the line \(A B\) are equal, is

A straight line through the vertex \(P\) of a \(\triangle P Q R\) intersects the side \(Q R\) at the point \(S\) and the circumcircle of the \(\triangle P Q R\) at the point \(T\). If \(S\) is not the centre of the circumcircle, then

A radioactive sample \(S_1\) having an activity of \(5 \mu \mathrm{Ci}\) has twice the number of nuclei as another sample \(S_2\) which has an activity of \(10 \mu \mathrm{Ci}\). The half lives of \(S_1\) and \(S_2\) can be