JEE Advanced · Chemistry · 13. GOC
In the Newman projection for 2,2-dimethylbutane

\(X\) and \(Y\) can respectively be
- A \(\mathrm{H}\) and \(\mathrm{H}\)
- B \(\mathrm{H}\) and \(\mathrm{C}_2 \mathrm{H}_5\)
- C \(\mathrm{C}_2 \mathrm{H}_5\) and \(\mathrm{H}\)
- D \(\mathrm{CH}_3\) and \(\mathrm{CH}_3\)
Answer & Solution
Correct Answer
(D) \(\mathrm{CH}_3\) and \(\mathrm{CH}_3\)
Step-by-step Solution
Detailed explanation

Conformation projection along \(\mathrm{C}_1-\mathrm{C}_2\)
\(\mathrm{C}_1\) contains all three \(\mathrm{Hs}\)
So, \(\quad X=\mathrm{H}\)

\(\mathrm{C}_2\) contains two methyl and one ethyl group
So, \(\quad Y=\mathrm{C}_2 \mathrm{H}_5\)
Conformational projection along
\(
\mathrm{C}_2-\mathrm{C}_3
\)
\(\mathrm{C}_2\) contains three methyl groups
\(\left(\mathrm{C}_2\right.\) form back carbon in the given structure)
So, \(\quad Y=\mathrm{CH}_3\)

\(\mathrm{C}_3\) contains two Hs and one methyl group
\(\left(\mathrm{C}_3\right.\) form front carbon in the given structure)
So, \(\quad X=\mathrm{CH}_3\)
\(\mathrm{C}_3\) contains two Hs and one methyl group
\(\left(\mathrm{C}_3\right.\) form front carbon in the given structure)
So, \(\quad X=\mathrm{CH}_3\)
Isomerism (Stereochemistry)
Conceptual (Structural visualisation) III
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