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Schemes \(1\) and \(2\) describe sequential transformation of alkynes \(\mathbf{M}\) and \(\mathbf{N}\). Consider only the major products formed in each step for both the schemes.



Question:
The correct statement with respect to product \(\mathbf{Y}\) is

Based on VSEPR theory, the number of 90 degree \(\mathrm{F}-\mathrm{Br}-\mathrm{F}\) angles in \(\mathrm{BrF}_5\) is

Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. \(\mathrm{NaOH}\) solution, gives \(\mathbf{P}\) and \(\mathbf{Q}\). Compound \(\mathbf{P}\) does not give Tollens' test, whereas \(\mathbf{Q}\) on acidification gives positive Tollens' test. Treatment of \(\mathbf{P}\) with excess cyclohexanone in the presence of catalytic amount of \(p\)-toluenesulfonic acid (PTSA) gives product \(\mathbf{R}\).
Sum of the number of methylene groups \(\left(-\mathrm{CH}_2-\right)\) and oxygen atoms in \(\mathbf{R}\) is ________.

Assuming that Hund's rule is violated, the bond order and magnetic nature of the diatomic molecule \(\mathrm{B}_2\) is

In a conductometric titration, small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration, and the conductance is measured after each addition.
The limiting ionic conductivity \(\left(\Lambda_0\right)\) values (in \(\mathrm{mS} \mathrm{m}^2 \mathrm{~mol}^{-1}\)) for different ions in aqueous solutions are given below:

For different combinations of titrates and titrants given in List-I, the graphs of 'conductance' versus 'volume of titrant' are given in List-II.
Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

Ozonolysis of ${\mathrm{ClO}}_2$ produces an oxide of chlorine. The average oxidation state of chlorine in this oxide is ______ .

Scheme $1$ and $2$ describe the conversion of $\mathrm{P}$ to $\mathrm{Q}$ and $\mathrm{R}$ to $\mathrm{S},$ respectively. Scheme $3$ describes the synthesis of $\mathrm{T}$ from $\mathrm{Q}$ and $\mathrm{S}.$ The total number of $\mathrm{B}\mathrm{r}$ atoms in a molecule of $\mathrm{T}$ is
Scheme $1$:

Scheme $2$:

Scheme$3$:

Let \(\overrightarrow{O P}=\frac{\alpha-1}{\alpha} \hat{i}+\hat{j}+\hat{k}, \overrightarrow{O Q}=\hat{i}+\frac{\beta-1}{\beta} \hat{j}+\hat{k}\) and \(\overrightarrow{O R}=\hat{i}+\hat{j}+\frac{1}{2} \hat{k}\) be three vectors, where \(\alpha, \beta \in \mathbb{R}-\{0\}\) and \(O\) denotes the origin. If \((\overrightarrow{O P} \times \overrightarrow{O Q}) \cdot \overrightarrow{O R}=0\) and the point \((\alpha, \beta, 2)\) lies on the plane \(3 x+3 y-z+l=0\), then the value of \(l\) is ____

Two identical glass rods ${\mathrm{S}}_1$ and ${\mathrm{S}}_2$ (refractive index = 1.5) have one convex end of radius of curvature 10 cm. They are placed with the curved surfaces at a distance d as shown in the figure, with their axes (shown by the dashed line) aligned. When a point source of light $\mathrm{P}$ is placed inside rod ${\mathrm{S}}_1$ on its axis at a distance of 50 cm from the curved face, the light rays emanating from it are found to be parallel to the axis inside ${\mathrm{S}}_2$ . The distance $\mathrm{d}$ is

The correct statement(s) regarding,
(i) $\mathrm{H}\mathrm{C}\mathrm{l}\mathrm{O}$
(ii) $\mathrm{H}\mathrm{C}\mathrm{l}{\mathrm{O}}_2$
(iii) $\mathrm{H}\mathrm{C}\mathrm{l}{\mathrm{O}}_3$ and
(iv) $\mathrm{H}\mathrm{C}\mathrm{l}{\mathrm{O}}_4$ is /are

Match List I with List II and select the correct answer using the code given below the lists :
 

	List - I		List - II
A.	${\left(\frac{1}{{\text{y}}^2}\left(\frac{\text{cos}\left({\text{tan}}^{-1}\text{y}\right)+\text{y sin}\left({\text{tan}}^{-1}\text{y}\right)}{\text{cot}\left({\text{sin}}^{-1}\text{y}\right)+\text{tan}\left({\text{sin}}^{-1}\text{y}\right)}\right)+{\text{y}}^4\right)}^{1/2}takes\; value$	P.	$\frac{1}{2}\sqrt{\frac{5}{3}}$
B.	​If cosx + cosy + cosz = 0 = sinx + siny + sinz then possible value of cos $\frac{\text{x}-\text{y}}{2}is$	Q.	$\sqrt{2}$
C.	If cos $\left(\frac{\pi }{4}-\text{x}\right)$ cos2x + sinx sin 2x secx = cosx sin2x secx + cos $\left(\frac{\pi }{4}+\text{x}\right)$ cos2x then possible value of secx is	R.	$\frac{1}{2}$
D.	If cot $\left({\text{sin}}^{-1}\sqrt{1-{\text{x}}^2}\right)=\text{sin}\left({\text{tan}}^{-1}\left(\text{x}\sqrt{6}\right)\right)\text{,}x\ne 0\text{,}$  then possible value of x is	S.	1

The potential energy of a particle of mass m at a distance r from a fixed point O is given by $V\left(r\right)=k{r}^2/2$, where k is a positive constant of appropriate dimensions. This particle is moving in a circular orbit of radius R about the point O. If v is the speed of the particle and L is the magnitude of its angular momentum about O, which of the following statements is (are) true?

The number of $4$-digit integers in the closed interval $\left[2022,4482\right]$ formed by using the digits $0,2,3,4,6,7$ is ______.