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An aqueous solution of metal ion \(\mathbf{M} 1\) reacts separately with reagents \(\mathbf{Q}\) and \(\mathbf{R}\) in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral complexes with these reagents. Aqueous solution of \(\mathbf{M} 2\) on reaction with reagent \(\mathbf{S}\) gives white precipitate which dissolves in excess of \(\mathbf{S}\). The reactions are summarized in the scheme given below:


Question:
Reagent \(\mathbf{S}\) is

The reagent(s) that can selectively precipitate ${\mathrm{S}}^{2-}$ from a mixture of ${\mathrm{S}}^{2-}$ and $\mathrm{S}{\mathrm{O}}_4^{2-}$ in aqueous solution is (are)

With respect to graphite and diamond, which of the statement(s) given below is (are) correct?

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The freezing point of the solution \(M\) is

Consider the following complex ions, P, Qand R.

The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is

Atoms of metals $\mathrm{x}, \mathrm{y}$ and $\mathrm{z}$ form face-centred cubic (fcc) unit cell of edge length ${\mathrm{L}}_{\mathrm{x}}$, body-centred cubic (bcc) unit cell of edge length ${\mathrm{L}}_{\mathrm{y}}$, and simple cubic unit cell of edge length ${\mathrm{L}}_{\mathrm{z}}$, respectively. If ${\mathrm{r}}_{\mathrm{z}}=\frac{\sqrt{3}}{2}{\mathrm{r}}_{\mathrm{y}};{\mathrm{r}}_{\mathrm{y}}=\frac{8}{\sqrt{3}}{\mathrm{r}}_{\mathrm{x}};{\mathrm{M}}_{\mathrm{z}}=\frac{3}{2}{\mathrm{M}}_{\mathrm{y}}$ and ${\mathrm{M}}_{\mathrm{z}}=3{\mathrm{M}}_{\mathrm{x}}$, then the correct statement(s) is(are)
[Given: ${\mathrm{M}}_{\mathrm{x}},{\mathrm{M}}_{\mathrm{y}}$, and ${\mathrm{M}}_{\mathrm{z}}$ are molar masses of metals $\mathrm{x}, \mathrm{y}$, and $z$, respectively. ${\mathrm{r}}_{\mathrm{x}},{\mathrm{r}}_{\mathrm{y}}$, and ${\mathrm{r}}_{\mathrm{z}}$ are atomic radii of metals $\mathrm{x},\mathrm{y}$, and $\mathrm{z}$, respectively.]

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A tertiary alcohol \(H\) upon acid catalysed dehydration gives a product \(I\). Ozonolysis of I leads to compounds \(\mathrm{J}\) and \(\mathrm{K}\). Compound \(\mathrm{J}\) upon reaction with
\(\mathrm{KOH}\) gives benzyl alcohol and a compound \(\mathrm{L}\), where \(\mathrm{K}\) on reaction with \(\mathrm{KOH}\) gives only \(M\).

Question:
The structures of compounds \(J, K\) and \(L\), respectively, are

Equation of the plane containing the straight line \(\frac{x}{2}=\frac{y}{3}=\frac{z}{4}\) and perpendicular to the plane containing the straight lines \(\frac{x}{3}=\frac{y}{4}=\frac{z}{2}\) and \(\frac{x}{4}=\frac{y}{2}=\frac{z}{3}\) is

In the following reaction sequence, the major product \(\mathbf{P}\) is formed.

Glycerol reacts completely with excess \(\mathbf{P}\) in the presence of an acid catalyst to form \(\mathbf{Q}\). Reaction of \(\mathbf{Q}\) with excess \(\mathrm{NaOH}\) followed by the treatment with \(\mathrm{CaCl}_2\) yields Ca-soap \(\mathbf{R}\), quantitatively. Starting with one mole of \(\mathbf{Q}\), the amount of \(\mathbf{R}\) produced in gram is ________.
[Given, atomic weight: \(\mathrm{H}=1, \mathrm{C}=12,\) \(\mathrm{~N}=14, \mathrm{O}=16, \mathrm{Na}=23, \mathrm{Cl}=35,\) \(\mathrm{Ca}=40\)]

The reaction of \(P_2\) with \(X\) leads selectively to \(\mathrm{P}_4 \mathrm{O}_6\). The \(\mathrm{X}\) is

Two non-conducting spheres of radii $R_1$ and $R_2$ and carrying uniform volume charge densities $+\rho$ and $-\rho$, respectively, are placed such that they partially overlap, as shown in the figure. At all points in the overlapping region,

Match the complexes in Column I with their properties listed in Column II. Indicate your answer by darkening the appropriate bubbles of the \(4 \times 4\) matrix given in the ORS.

Column I	Column II
A. \(\text O _2^{-} \longrightarrow \text{O} _2\) \(+~\text O _2^{2-}\)	P. Redox reaction
B. \(\text{CrO} _4^{2-}+\text H ^{+} \longrightarrow\)	Q. One of the products has trigonal planar structure
C. \(\text{MnO} _4^{-}+ \text{NO} _2^{-}\) \(+~ \text H ^{+} \longrightarrow\)	R. Dimeric bridged tetrahedral metal ion
D. \(\text{NO} _3^{-}+ \text H _2 \text{SO} _4\) \(+~ \text{Fe} ^{2+} \longrightarrow\)	S. Disproportionation

In dilute aqueous ${\mathrm{H}}_2\mathrm{S}{\mathrm{O}}_4$ , the complex diaquodioxalatoferrate (II) is oxidized by ${\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}$ . For this reaction, the ratio of the rate of change of $\left[{\mathrm{H}}^{+}\right]$ to the rate of change of $\left[{\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}\right]$ is