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JEE Advanced · Chemistry · 23. Coordination Compounds

Match the complexes in Column I with their properties listed in Column II. Indicates your answer by darkening the appropriate bubbles of \(4 \times 4\) matrix given in the ORS.

  1. A A-p, r; B-p, q, s; C-p; D-q, r
  2. B A-p, s; B-p, r, s; C-p, s; D-q, r
  3. C A-p, q, s; B-p, r, s; C-q, s; D-q, s
  4. D A-r, s; B-q; C-p; D-p, q, s
Verified Solution

Answer & Solution

Correct Answer

(C) A-p, q, s; B-p, r, s; C-q, s; D-q, s

Step-by-step Solution

Detailed explanation

(A) \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\left[\left(\mathrm{H}_2 \mathrm{O}\right)_2\right] \mathrm{Cl}_2 p, q, s\right.\)
Oxidation state \(\mathrm{Co}\) is \(+2\)
\(\Rightarrow\) Paramagnetic, exhibits geometrical isomerism.
(B) \(\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] p, r, s\)
\(\mathrm{dsp}{ }^2\)-hybridisation
\(\mathrm{Pt}^{2+}\), diamagnetic square planar, geometrical isomerism
(C) \(q, s\) (D) \(q, s\)
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