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JEE Advanced · Chemistry · 13. GOC

Image (isomeric products) \(\text C _5\text H _{11} \text{Cl} \xrightarrow{\text { fractional distillation }}\text M\) (isomeric products)
What are N and M ?

  1. A 6,6
  2. B 6,4
  3. C 4,4
  4. D 3, 3
Verified Solution

Answer & Solution

Correct Answer

(B) 6,4

Step-by-step Solution

Detailed explanation



In these, (iii) and (iv) are enantiomers and (v) and (vi) are also enantiomers to each other. Thus total six isomers will be possible for \(N\). In these only four isomers will be obtained on fractional distillation without resolution because \(d\) and \(l\) isomers (i.e., (iii) \& (iv) and (v) \& (vi)) cannot be separated by fractional distillation. Hence \(N=6\) and \(M=4\).
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