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JEE Advanced · Chemistry · 22. d & f Block

In the scheme given below, \(\text X\) and \(\text Y\), respectively, are
Metal halide \(\quad \xrightarrow{\text { aq. NaOH} } \quad\) White precipitate \((\text P )+\) Filtrate \((\text Q )\)
\(P \xrightarrow[\text { heat }]{\substack{\text { aq. } H _2 SO _4 \\ PbO _2 \text { (excess) }}}\text X\) (a coloured species in solution)
\(Q \xrightarrow[\text { warm }]{ MnO ( OH )_2, \text { Conc. } H _2 SO _4}\text Y\) (gives blue-coloration with KI-starch paper)

  1. A CrO42- and Br2
  2. B MnO42- and   Cl2
  3. C MnO4-  and   Cl2
  4. D MnSO4  and  HOCl
Verified Solution

Answer & Solution

Correct Answer

(C) MnO4-  and   Cl2

Step-by-step Solution

Detailed explanation

The metal halide can be manganese dichloride. It gives white precipitate of manganese hydroxide. MnCl2aq.NaOHMnOH2P+NaClQ
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