For the elementary reaction $\mathrm{M}\to \mathrm{N}$, the rate of disappearance of $\mathrm{M}$ increases by a factor of $8$ upon doubling the concentration of $\mathrm{M}$. The order of the reaction with respect to $\mathrm{M}$ is

In a bimolecular reaction, the steric factor $\mathrm{P}$ was experimentally determined to be $4.5$. The correct option(s) among the following is(are)

For the following electrochemical cell at $\text{289 K,}$
\(\operatorname{Pt}( s ) \mid H _2(g, 1\) bar \() \mid H ^{+}( aq , 1 M ) \| M ^{4+}(\) aq. \(), M ^{2+}(\) aq. \() \mid \operatorname{Pt}( s )\)
${\mathrm{E}}_{\mathrm{c}\mathrm{e}\mathrm{l}\mathrm{l}}=0.092\mathrm{ }\mathrm{V}$ when $\frac{\left[{\mathrm{M}}^{2+}\left(\mathrm{a}\mathrm{q}.\right)\right]}{\left[{\mathrm{M}}^{4+}\left(\mathrm{a}\mathrm{q}.\right)\right]}={10}^{\mathrm{x}}$
Given: ${\mathrm{E}}_{{\mathrm{M}}^{4+}/{\mathrm{M}}^{2+}}^0=0.151\mathrm{ }\mathrm{V}\mathrm{ };2.303\frac{\mathrm{R}\mathrm{T}}{\mathrm{F}}=0.059$
The value of $\text{x}$ is -

The conductance of $0.0015\mathrm{ }\mathrm{M}$ aqueous solution of a weak monobasic acid was determined by using a conductivity cell consisting of platinized $\mathrm{Pt}$electrodes. The distance between the electrodes is $120\mathrm{ }\mathrm{cm}$ with an area of cross-section of $1 {\mathrm{cm}}^2$. The conductance of this solution was found to be $5\times {10}^{-7}\mathrm{S}$ . The $\mathrm{pH}$of the solution is $4$. The value of limiting molar conductivity of this weak monobasic acid in aqueous solution is $\mathrm{ }\mathrm{Z}\mathrm{ }\times \mathrm{ }{10}^2\mathrm{S}\mathrm{ }{\mathrm{cm}}^{-1}{\mathrm{mol}}^{-1}.$ The value of $\mathrm{Z}$is.

The option(s) with correct sequence of reagents for the conversion of \(\mathbf{P}\) to \(\mathbf{Q}\) is(are) :

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The reactions of \(\mathrm{Cl}_{2}\) gas with cold-dilute and hot-concentrated \(\mathrm{NaOH}\) in water give sodium salts of two (different) oxoacids of chlorine, \(\boldsymbol{P}\) and \(\boldsymbol{Q}\), respectively. The \(\mathrm{Cl}_{2}\) gas reacts with \(\mathrm{SO}_{2}\) gas, in presence of charcoal, to give a product \(\boldsymbol{R}\). \(\boldsymbol{R}\) reacts with white phosphorus to give a compound \(\boldsymbol{S}\). On hydrolysis, \(\boldsymbol{S}\) gives an oxoacid of phosphorus, \(\boldsymbol{T}\).
Question:
\(R, S\) and \(T\), respectively, are

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p-amino-N, N-dimethylaniline is added to a strongly acidic solution of \(X\). The resulting solution is treated with a few drops of aqueous solution of \(Y\) to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of \(Y\) with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves an excess addition of the reagent. Similarly, treatment of the solution of \(Y\) with the solution of potassium hexacyanoferrate(III) leads to a brown colouration due to the formation of \(Z\).
Question:
The compound \(X\), is

An electron in a hydrogen atom undergoes a transition from an orbit with a quantum number $n_i$ to another quantum number $n_f$ . $V_i \text{and} V_f$ are the initial and final potential energies of the electron. If $\frac{V_i}{V_f}=6.25$ then the smallest $n_f$ is

The mole fraction of a solute in a solution is $0.1$. At $298 \mathrm{K}$, the molarity of this solution is the same as its molality. The density of this solution at $298 \mathrm{K}$ is $2.0\mathrm{ }\mathrm{g}\mathrm{ }\mathrm{c}{\mathrm{m}}^{–3}$. The ratio of the molecular weights of the solute and solvent, $\left(\frac{\mathrm{M}{\mathrm{W}}_{\mathrm{s}\mathrm{o}\mathrm{l}\mathrm{u}\mathrm{t}\mathrm{e}}}{\mathrm{M}{\mathrm{W}}_{\mathrm{s}\mathrm{o}\mathrm{l}\mathrm{v}\mathrm{e}\mathrm{n}\mathrm{t}}}\right)$, is:

A point mass is subjected to two simultaneous sinusoidal displacements in \(x\)-direction, \(x_1(t)=A \sin \omega t\) and \(x_2(t)=A \sin \left(\omega t+\frac{2 \pi}{3}\right)\). Adding a third sinusoidal displacement \(x_3(t)=B \sin (\omega t+\phi)\) bring the mass to a complete rest. The values of \(B\) and \(\phi\) are

A solution of colourless salt \(\mathrm{H}\) on boiling with excess \(\mathrm{NaOH}\) produces a non-flammable gas. The gas evolution ceases after sometime. Upon addition of \(\mathrm{Zn}\) dust to the same solution, the gas evolution restarts. The colourless salt (s) \(\mathrm{H}\) is (are)

If ${\mathrm{\lambda }}_{\mathrm{c}\mathrm{u}}$ is the wavelength of ${\mathrm{K}}_{\mathrm{\alpha }}$ X-ray line of copper (atomic number 29) and ${\mathrm{\lambda }}_{\mathrm{M}\mathrm{o}}$ is the wavelength of the ${\mathrm{K}}_{\mathrm{\alpha }}$ X-ray line of molybdenum (atomic number 42), then the ratio $\frac{{\mathrm{\lambda }}_{\mathrm{c}\mathrm{u}}}{{\mathrm{\lambda }}_{\mathrm{M}\mathrm{o}}}$ is close to

5.00 mL of 0.10 M oxalic acid solution taken in a conical flask is titrated against NaOH from a burette using phenolphthalein indicator. The volume of NaOH required for the appearance of permanent faint pink color is tabulated below for five experiments. What is the concentration, in molarity, of the NaOH solution?

Exp. No.	Vol. of NaOH (mL)
1	12.5
2	10.5
3	9.0
4	9.0
5	9.0