Among \(\left[ Ni ( CO )_4\right],\left[ NiCl _4\right]^{2-},\left[ Co \left( NH _3\right)_4 Cl _2\right] Cl , Na _3\) \(\left[ CoF _6\right], Na _2 O _2\) and \(CsO _2\), the total number of paramagnetic compounds is

Statement I Micelles are formed by surfactant molecules above the critical micellar concentration (CMC).
Statement II The conductivity of a solution having surfactant molecules deceases sharply at the CMC.

The amount of water produced ($\mathrm{in} \mathrm{g}$) in the oxidation of $1$ $\mathrm{mole}$of rhombic sulphur by conc. ${\mathrm{H}\mathrm{N}\mathrm{O}}_3$ to a compound with the highest oxidation state of sulphur is
(Given data: Molar mass of water$=18\mathrm{ }\mathrm{g}\mathrm{ }{\mathrm{m}\mathrm{o}\mathrm{l}}^{-1}$ )

A solution of a metal ion when treated with \(\mathrm{KI}\) gives a red precipitate which dissolved in excess KI to give a colourless solution. Moreover, the solution of metal ion on treatment with a solution of cobalt (II) thiocyanate gives rise to a deep blue crystalline precipitqte. The metal ion is

For the cell $\mathrm{Zn} \left(\mathrm{s}\right)\left|{\mathrm{ZnSO}}_4 \left(\mathrm{aq}\right)\right|\left|{\mathrm{CuSO}}_4 \left(\mathrm{aq}\right)\right|\mathrm{Cu} \left(\mathrm{s}\right)$, when the concentration of ${\mathrm{Zn}}^{2+}$ is $10$ times the concentration of ${\mathrm{Cu}}^{2+}$, the expression for $\mathrm{\Delta G} \left(\mathrm{in}\mathrm{ }\mathrm{J}\mathrm{ }{\mathrm{mol}}^{-1}\right)$ is
$[\mathrm{F}=$Faraday's constant, $\mathrm{R}=$universal gas constant, $\mathrm{T}=$temperature, ${\mathrm{E}}^{\mathrm{o}}\mathrm{cell}=1.1\mathrm{V}]$

Match the specified conditions in solids listed in Column I with their properties in Column II. Indicate your answer by darkening the appropriate bubbles of the \(4 \times 4\) matrix given in the ORS.

Column I	Column II
A. Simple cubic and face-centered cubic	p. Have these cell parameters \(a=b=c \text { and } \alpha=\beta=\gamma\)
B. Cubic and rhombohedral	q. Are two crystal systems
C. Cubic and tetragonal	r. Have only two crystallographic angles of \(90^{\circ}\)
D. Hexagonal and monoclinic	s. Belong to same crystal system

The total number of possible isomers for $\left[\mathrm{Pt}{\left({\mathrm{NH}}_3\right)}_4{\mathrm{Cl}}_2\right]{\mathrm{Br}}_2$ is___.

Let \(\alpha(a)\) and \(\beta(a)\) be the roots of the equation \((\sqrt[3]{1+a}-1) x^{2}+(\sqrt{1+a}-1) x+(\sqrt[6]{1+a}-1)=0\) where \(a\) \(>-1\). Then \(\lim _{a \rightarrow 0^{+}} \alpha(a)\) and \(\lim _{x \rightarrow 0^{+}} \beta(a)\) are

Let \(X=\left({ }^{10} C_1\right)^2+2\left({ }^{10} C_2\right)^2+3\left({ }^{10} C_3\right)^2+\ldots+\) \(10\left({ }^{10} C_{10}\right)^2\), where \({ }^{10} C_r, r \in\{1,2, \ldots, 10\}\) denote binomial coefficients. Then, the value of \(\frac{1}{1430} X\) is _____________.

A thin uniform annular disc (see figure) of mass \(M\) has outer radius \(4 R\) and inner radius \(3 R\). The work required to take a unit mass from point \(P\) on its axis to infinity is

Paragraph:
If the measurement errors in all the independent quantities are known, then it is possible to determine the error in any dependent quantity. This is done by the use of series expansion and truncating the expansion at the first power of the error. For example, consider the relation $z =\frac{x}{y}$. If the errors in $x, y \mathrm{a}\mathrm{n}\mathrm{d} z \mathrm{a}\mathrm{r}\mathrm{e} ∆x, ∆y \mathrm{a}\mathrm{n}\mathrm{d} ∆z$ , respectively, then

$z\pm ∆z=\frac{x\pm ∆x}{y\pm ∆y}=\frac{x}{y}\left(1\pm \frac{∆x}{x}\right){\left(1\pm \frac{∆y}{y}\right)}^{-1}$

The series expansion for ${\left(1\pm \frac{∆y}{y}\right)}^{-1}$, to first power in $∆y/y, \mathrm{i}\mathrm{s} 1\mp \left(∆y/y\right)$. The relative errors in independent variables are always added. So the error in $z$ will be

$\text{Δ}z=z\left(\frac{\text{Δ}x}{x}+\frac{\text{Δ}y}{y}\right).$
Question :
The above derivation makes the assumption that $\frac{\text{Δ}r}{x}\ll 1,\frac{\text{Δ}y}{y}\ll 1$. Therefore, the higher powers of these quantities are neglected.

Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes (I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.

	List – I		List – II
A.		P.
B.		Q.
C.		R.
D.		S.

Paragraph:
p-amino-N, N-dimethylaniline is added to a strongly acidic solution of \(X\). The resulting solution is treated with a few drops of aqueous solution of \(Y\) to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of \(Y\) with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves an excess addition of the reagent. Similarly, treatment of the solution of \(Y\) with the solution of potassium hexacyanoferrate(III) leads to a brown colouration due to the formation of \(Z\).
Question:
The compound \(Y\), is