A trinitro compound, $1,3,5$-tris-($4$-nitrophenyl) benzene, on complete reaction with an excess of $\mathrm{Sn}/\mathrm{HCl}$ gives a major product, which on treatment with an excess of ${\mathrm{NaNO}}_2/\mathrm{HCl}$ at $0°\mathrm{C}$ provides $\mathbf{P}$ as the product. $\mathbf{P}$, upon treatment with excess of ${\mathrm{H}}_2\mathrm{O}$ at room temperature, gives the product $\mathbf{Q}$. Bromination of $\mathbf{Q}$ in aqueous medium furnishes the product $\mathbf{R}$. The compound $\mathbf{P}$ upon treatment with an excess of phenol under basic conditions gives the product $\mathbf{S}$. The molar mass difference between compounds $\mathbf{Q}$ and $\mathbf{R}$ is $474 \mathrm{g} {\mathrm{mol}}^{-1}$ and between compounds $\mathbf{P}$ and $\mathbf{S}$ is $172.5 \mathrm{g} {\mathrm{mol}}^{-1}$.
The total number of carbon atoms and heteroatoms present in one molecule of \(S\) is
[Use: Molar mass (in \(\text{gmol} ^{-1}\) ): \(\text H =1,\text C =12,\text N=14,\text O =16,\) \(\text{Br} =80, \text{Cl} =35.5\) Atoms other than C and H are considered as heteroatoms]

LIST-I contains compounds and LIST-II contains reactions

List - I	List - II
(I) \(H _2 O _2\)	(P) \(Mg \left( HCO _3\right)_2+ Ca\) \((OH)_2 \rightarrow\)
(II) \(Mg ( OH )_2\)	(Q) \(BaO _2+ H _2 SO _4 \rightarrow\)
(III) \(BaCl _2\)	(R) \(Ca \left( OH _2\right) 2\) \(+ MgCl _2 \rightarrow\)
(IV) \(CaCO _3\)	(S) \(BaO _2+ HCl \rightarrow\)
	(T) \(Ca \left( HCO _3\right)_2\) \(+ Ca ( OH )_2\)

Match each compound in LIST-I with its formation reaction(s) in LIST-II, and choose the correct option

In the following reaction sequence in aqueous solution, the species $\text{X,}\text{Y}$ and $\text{Z}$ respectively, are
\(S _2 O _3^{2-} \xrightarrow{ Ag ^{+}} \underset{\substack{\text { Clear } \\ \text { Solution }}}{ X } \xrightarrow{ Ag ^{+}} \underset{\substack{\text { White } \\ \text { Precipitate }}}{ Y }\) \(\xrightarrow{\text { With time }} \underset{\substack{\text { Black } \\ \text { Precipitate }}}{ Z }\)

The calculated spin only magnetic moments of ${\left[\mathrm{Cr}{\left({\mathrm{NH}}_3\right)}_6\right]}^{3+}$ and ${\left[{\mathrm{CuF}}_6\right]}^{3-}$ in $\mathrm{BM},$ respectively, are (Atomic numbers of $\mathrm{Cr}$ and $\mathrm{Cu}$ are $24$ and $29,$ respectively)

The entropy versus temperature plot for phases $\alpha$ and $\beta$ at $1$ bar pressure is given. ${\mathrm{S}}_{\mathrm{T}}$ and ${\mathrm{S}}_0$ are entropies of the phases at temperatures $\mathrm{T}$ and $0 \mathrm{K}$, respectively. The transition temperature for $\alpha$ to $\beta$ phase change is $600 \mathrm{K}$ and ${\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}-{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}=1 \mathrm{J} {\mathrm{mol}}^{-1} {\mathrm{K}}^{-1}$. Assume $\left({\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}-{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}\right)$ is independent of temperature in the range of $200$ to $700 \mathrm{K}.{\mathrm{C}}_{\mathrm{p},\mathrm{\alpha }}$ and ${\mathrm{C}}_{\mathrm{p},\mathrm{\beta }}$ are heat capacities of $\alpha$ and $\beta$ phases, respectively.
The value of entropy change, ${\mathrm{S}}_{\beta }-{\mathrm{S}}_{\alpha }$ (in ${\mathrm{Jmol}}^{-1} {\mathrm{K}}^{-1}$ ), at $300 \mathrm{K}$ is [Use: $\ln 2=0.69$0. Given: ${\mathrm{S}}_{\beta }-{\mathrm{S}}_{\alpha }=0$ at $0 \mathrm{K}$]

Monocyclic compounds \(\mathbf{P}, \mathbf{Q}, \mathbf{R}\) and \(\mathbf{S}\) are the major products formed in the reaction sequences given below.


The product having the highest number of unsaturated carbon atom(s) is-

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The freezing point of the solution \(M\) is

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The circle \(x^2+y^2-8 x=0\) and hyperbola \(\frac{x^2}{9}-\frac{y^2}{4}=1\) intersect at the points \(A\) and \(B\).Question:
Equation of the circle with \(A B\) as its diameter is

The value of ${\left({\left({\log }_{2}9\right)}^2\right)}^{\frac{1}{{\log }_2\left({\log }_{2}9\right)}}\times {\left(\sqrt{7}\right)}^{\frac{1}{{\log }_{4}7}}$ is_____.

The probability that a missile hits a target successfully is $0.75.$ In order to destroy the target completely, at least three successful hits are required. Then the minimum number of missiles that have to be fired so that the probability of completely destroying the target is not less than $0.95,$ is ___________

The wavelength of the first spectral line in the Balmer series of hydrogen atom is \(6561 Å\). The wavelength of the second spectral line in the Balmer series of singly ionized helium atom is

A straight line through the vertex \(P\) of a \(\triangle P Q R\) intersects the side \(Q R\) at the point \(S\) and the circumcircle of the \(\triangle P Q R\) at the point \(T\). If \(S\) is not the centre of the circumcircle, then

A circular disc with a groove along its diameter is placed horizontally. A block of mass \(1 \mathrm{~kg}\) is placed as shown. The coefficient of friction between the block and all surfaces of groove in contact is \(\mu=2 / 5\). The disc has an acceleration of \(25 \mathrm{~m} / \mathrm{s}^2\). Find the acceleration of the block with respect to disc.