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AP EAMCET · Chemistry · Haloalkanes and Haloarenes

Which of the following statements are correct?
A. The \(\mathrm{C}-\mathrm{Cl}\) bond in chlorobenzene is shorter than in chloromethane.
B. It is difficult to replace chlorine from chlorobenzene than from benzyl chloride.
C. The \(\mathrm{C}-\mathrm{Cl}\) bond in chlorobenzene has some double bond character.
D. Chlorobenzene on chlorination gives m-dichlorobenzene

  1. A A, B, C
  2. B A, D only
  3. C B, C, D
  4. D C, D only
Verified Solution

Answer & Solution

Correct Answer

(A) A, B, C

Step-by-step Solution

Detailed explanation

Chlorobenzene has double bond character between \(\mathrm{C}\) and \(\mathrm{Cl}\). So, it is difficult to replace form than form benzyl chloride. (c) \(\mathrm{C}-\mathrm{Cl}\) has double bond character in chlorobenzene. (d) Chlorobenzene on chlorination gives…
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