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AP EAMCET · Chemistry · General Organic Chemistry

Arrange the following carbocations in the increasing order of stability with respect to their labels.
\(\begin{array}{c|c}
\hline \text { Label } & \text { Carbocation } \\
\hline 1 & \left(\mathrm{CH}_3\right)_2 \mathrm{CH}^{+} \\
\hline 2 & \mathrm{CH}_3^{+} \\
\hline 3 & \left(\mathrm{CH}_3\right)_3 \mathrm{C}^{+} \\
\hline 4 & \mathrm{CH}_3-\mathrm{CH}_2^{+} \\
\hline
\end{array}\)

  1. A \(2 < 4 < 1 < 3\)
  2. B \(1 < 2 < 3 < 4\)
  3. C \(4 < 3 < 2 < 1\)
  4. D \(2 < 4 < 3 < 1\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(2 < 4 < 1 < 3\)

Step-by-step Solution

Detailed explanation

Stability of carbocation \(\propto\) number of hyperconjugative structure \(\propto\) number of \(\alpha-\mathrm{H}\) atoms (1) \(\stackrel{\alpha}{\mathrm{C}} \mathrm{H}_3-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\stackrel{\alpha}{\mathrm{C}} \mathrm{H}_3\), Hyperconjugative…