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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

जब सांद्रित \(HCl\) को \(CoCl _{2}\) के जलीय घोल में मिलाया गया, तब उसका रंग रक्ताभ गुलाबी से गाढ़ा नीला हो गया। इस अभिक्रिया में कौन सा संकुल आयन नीले रंग का कारण है ?

  1. A \({\left[ {CoC{l_4}} \right]^{2 - }}\)
  2. B \({\left[ {CoC{l_6}} \right]^{3 - }}\)
  3. C \({\left[ {CoC{l_6}} \right]^{4 - }}\)
  4. D \({\left[ {Co{{\left( {{H_2}O} \right)}_6}} \right]^{2 + }}\)
Verified Solution

Answer & Solution

Correct Answer

(A) \({\left[ {CoC{l_4}} \right]^{2 - }}\)

Step-by-step Solution

Detailed explanation

Aqueous of solution of \(CoCl_2\) contains \([Co(H_2O)_6]^{2+}\) which is pinkish in colour so option \((d)\) is incorrect. Reduction potential of \(C{o^{3 \oplus }} \to C{o^{2 \oplus }}\) is high so option \((b)\) is incorrect. \(Co^{2+}\) does not oxidises easily to…
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