दो यौगिक A तथा B जिनका आण्विक सूत्र \left( C _{3} H _{6} O \right) समान है, मेथिलमैग्नीशियम ब्रोमाइड़ के साथ ग्रिग्नार्ड अभिक्रिया करके उत्पाद C तथा D देते है। उत्पाद C तथा D निम्नलिखित रासायनिक परीक्षण देते है Test C D सेरिक अमोनियम नाइट्रेट परीक्षण सकारात्मक सकारात्मक लूकास परीक्षण 5 मिनट के बाद आविलता की प्राप्ति तुरंत आविलता की प्राप्ति आयोडोफार्म परीक्षण सकारात्मक नकारात्मक C तथा D क्रमशः है

Question

Accepted Answer

(C) \begin{array}{*{20}{c}} {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH} \ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \ {C = {H_3}C - C{H_2} - CH - C{H_3}} \end{array} D = {H_3}C - \begin{array}{*{20}{c}} {C{H_3}\,\,\,\,\,} \ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \ {C - OH} \ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \ {C{H_3}\,\,\,\,\,} \end{array}

Answer

(A) C = {H_3}C - \begin{array}{*{20}{c}} {C{H_3}\,\,\,\,\,\,\,\,} \ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \ {C - OH} \ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \ {C{H_3\,\,\,\,\,\,\,\,}} \end{array} \begin{array}{*{20}{c}} {D = {H_3}C - C{H_2} - CH - C{H_3}} \ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH} \end{array}

Answer

(B) C = H _{3} C - CH _{2}- C H _{2}- CH _{2}- OH D = {H_3}C - \begin{array}{*{20}{c}} {C{H_3}\,\,\,\,\,} \ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \ {C - OH} \ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \ {C{H_3}\,\,\,\,\,} \end{array}

Answer

(D) C = H _{3} C - CH _{2}- CH _{2}- CH _{2}- OH \begin{array}{*{20}{c}} {D = {H_3}C - C{H_2} - CH - C{H_3}} \ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH} \end{array}

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Test	\(C\)	\(D\)
सेरिक अमोनियम नाइट्रेट परीक्षण	सकारात्मक	सकारात्मक
लूकास परीक्षण	\(5\) मिनट के बाद आविलता की प्राप्ति	तुरंत आविलता की प्राप्ति
आयोडोफार्म परीक्षण	सकारात्मक	नकारात्मक